Pig Liver Esterase-catalyzed Hydrolysis of Three Diesters of meso-Bicyclic Dicarboxylic Acid and Three Tetraesters of Tetrahydrofuran-2,3,4,5-tetracarboxylic Acid

Chemical Research in Chinese Universities ›› 2000, Vol. 16 ›› Issue (4): 369-374.

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Pig Liver Esterase-catalyzed Hydrolysis of Three Diesters of meso-Bicyclic Dicarboxylic Acid and Three Tetraesters of Tetrahydrofuran-2,3,4,5-tetracarboxylic Acid

MA Guang-En¹, Tamm Ch.²

1. National Institutes of Pharmaceutical Research & Development, Beijing 102206, P. R. China;
2. Institut fur Organishe Chemie der Universitat Basel, CH-4056 Basel Switzerland

Received:1999-08-03 Online:2000-12-24 Published:2011-09-09
Supported by:
Supported by the National Natural Science Foundation of China and Schweizerischer National fonds Zur Forderunyder wissenschaftlichen Forschung.

Abstract

Abstract: Three diesters of exo- syn-meso-oxabicyclo (2, 2, 1)-hept-5-ene-2,3-dicarboxylic acid and three tetraesters of tetrahydrofuran-2, 3, 4, 5-tetracarboxylic acid were synthesized and tested with enantioselective hydrolysis catalyzed by pig liver esterase(PLE).The results of the PLEcatalyzed hydrolysis were discussed.

Key words: Oxabicyclo(2,2,1)-hept-5-ene-2,3-dicarboxylic acid, Tetrahydrofuran-2,3,4,5-tetracarboxylic acid, Esterification, Hydrolysis, Pig liver esterase(PLE)

MA Guang-En, Tamm Ch. . Pig Liver Esterase-catalyzed Hydrolysis of Three Diesters of meso-Bicyclic Dicarboxylic Acid and Three Tetraesters of Tetrahydrofuran-2,3,4,5-tetracarboxylic Acid[J]. Chemical Research in Chinese Universities, 2000, 16(4): 369-374.

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Pig Liver Esterase-catalyzed Hydrolysis of Three Diesters of meso-Bicyclic Dicarboxylic Acid and Three Tetraesters of Tetrahydrofuran-2,3,4,5-tetracarboxylic Acid

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