Synthesis of Poly (isosorbide carbonate) via Melt Polycondensation Catalyzed by a KF/MgO Catalyst

doi:10.1007/s40242-019-8356-6

Chemical Research in Chinese Universities ›› 2019, Vol. 35 ›› Issue (4): 721-728.doi: 10.1007/s40242-019-8356-6

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Synthesis of Poly (isosorbide carbonate) via Melt Polycondensation Catalyzed by a KF/MgO Catalyst

SHEN Xiaolong^1,2, LIU Shaoying¹, WANG Qingyin¹, ZHANG Hua¹, WANG Gongying^1,2

1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, P. R. China;
2. National Engineering Laboratory for VOCs Pollution Control Material & amp;Technology University of Chinese Academy of Sciences, Beijing 101408, P. R. China

Received:2018-11-12 Revised:2019-03-22 Online:2019-08-01 Published:2019-08-01
Contact: WANG Gongying E-mail:gywang@cioc.ac.cn
Supported by:
Supported by the National Key R&D Program of China(No.2016YFB0301900) and the Science and Technology Support Program of Sichuan Province, China(No.2015GZ0065).

Abstract

Abstract: MgO loaded with KF was prepared by using the impregnation method and was employed as the catalyst for the direct transesterification of diphenyl carbonate(DPC) with isosorbide to synthesize high-molecular-weight poly(isosorbide carbonate)(PIC). The relationship between physical-chemical properties and catalytic performance for KF/MgO in this melt process was investigated by various characterization techniques. The basic site amount and strength were found to be responsible for this transesterification process, and the medium and strong basic sites tended to promote the polycondensation reaction. 20-KF/MgO-500 exhibited the best catalytic performance, giving PIC with M_w of 84200 and glass transition temperature(T_g) of 173℃ under optimal conditions. Additionally, 20-KF/MgO-500 was found to catalyze the transerification of DPC with isosorbide and other diols to synthesize the corresponding poly(aliphatic diol-co-isosorbide carbonate)s(PAICs). This excellent activity can be ascribed to the presence of an abundance of basic sites and their specific basic strength on the surface of KF/MgO.

Key words: KF/MgO, Poly(isosorbide carbonate), Diphenyl carbonate, Transesterification, Solid base

SHEN Xiaolong, LIU Shaoying, WANG Qingyin, ZHANG Hua, WANG Gongying. Synthesis of Poly (isosorbide carbonate) via Melt Polycondensation Catalyzed by a KF/MgO Catalyst[J]. Chemical Research in Chinese Universities, 2019, 35(4): 721-728.

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Synthesis of Poly (isosorbide carbonate) via Melt Polycondensation Catalyzed by a KF/MgO Catalyst

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