Studies on Rate Enhancement of Polymerization in NMRP

Abstract

Abstract: In NMRP, the polymerization of MMA, the polymerization of St and the copolymerization of MMA with St were distinctly accelerated by the addition of a small amount of MN.The polymerization proceeds in a living fashion as indicated by the increase in molecular weight with the increase of time and conversion and a relatively low polydispersity.It has been found that the addition of MN results in a nearly one hundred times higher rate of the polymerization of MMA, a nearly twenty times higher rate of the polymerization of St and a nearly fifteen times higher rate of the copolymerization of St and MMA.

Key words: Rate enhancement, Living free radical polymerization, TEMPO, MN

HUANG Jian-ying, XU Miao-qing, YAN Ming-fa, CHEN Yi-hong, CHU Jia-yan, ZHUANG Jia-ming, DAI Li-zong, ZOU You-si. Studies on Rate Enhancement of Polymerization in NMRP[J]. Chemical Research in Chinese Universities, 2005, 21(6): 734-736.

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Studies on Rate Enhancement of Polymerization in NMRP

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