Solvothermal Synthesis, Crystal Structure and Photoluminescent Property of a Novel 3D [Ca2(HCOO)2(nds)(H2O)2]n

doi:10.1007/s40242-014-3414-6

Abstract

Abstract:

A novel calcium(Ⅱ) metal-organic framework [Ca₂(HCOO)₂(nds)(H₂O)₂]_n(1) with mixed 1,5-naphthalene-disulfonate sodium salt(1,5-nds) and formate as organic ligands has been obtained under solvothermal conditions. It was found that the μ₃-η₂:η₂ bridging mode of HCOO^- in compound 1 is uncommon. Moreover, the formate, which was in situ formed from N,N'-dimethylformamide, played an important role in the formation of 3D structure. HCOO^- ligands bridged Ca(Ⅱ) ions into grid-like layers that were further pillared by the 1,5-nds ligand to form a 3D Ca-based framework. Compound 1 also exhibits a strong blue luminescence at room temperature.

Key words: Naphthalenedisulfonate, Luminescence property, Metal-organic framework

WANG Shuang, ZHANG Renchun, WANG Junjie, SHEN Lanlan, ZENG Ying, ZHANG Daojun. Solvothermal Synthesis, Crystal Structure and Photoluminescent Property of a Novel 3D [Ca₂(HCOO)₂(nds)(H₂O)₂]_n[J]. Chemical Research in Chinese Universities, 2014, 30(1): 9-12.

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Solvothermal Synthesis, Crystal Structure and Photoluminescent Property of a Novel 3D [Ca₂(HCOO)₂(nds)(H₂O)₂]_n

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