Facile Synthesis of Fe-b ased MOFs(Fe-BTC) as Efficient Adsorbent for Water Purifications

doi:10.1007/s40242-019-8415-z

Chemical Research in Chinese Universities ›› 2019, Vol. 35 ›› Issue (4): 564-569.doi: 10.1007/s40242-019-8415-z

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Facile Synthesis of Fe-b ased MOFs(Fe-BTC) as Efficient Adsorbent for Water Purifications

HAN Qian¹, WANG Zumin¹, CHEN Xiaoyu¹, JIAO Chuangwei¹, LI Haiyan², YU Ranbo^1,3

1. Department of Physical Chemistry, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China;
2. School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, Beijing 100044, P. R. China;
3. Key Laboratory of Material Processing and Mold, Ministry of Education, Zhengzhou University, Zhengzhou 450001, P. R. China

Received:2018-12-28 Revised:2019-05-01 Online:2019-08-01 Published:2019-08-01
Contact: LI Haiyan, YU Ranbo E-mail:ranboyu@ustb.edu.cn;lihaiyan@bucea.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.51472025, 21671016, 51872024).

Abstract

Abstract: Fe-based metal-organic frameworks(Fe-BTC) were successfully synthesized in a large scale by using a simple one-pot method at room temperature. To understand its composition, texture and morphology, the as-synthesized material was analyzed systematically. Moreover, based on the adsorption property for anionic organic dyes(methyl orange, Congo red), cationic organic dyes(methylene blue, rhodamine B) and heavy metal ions(Pb²⁺) in aqueous solutions, it was revealed that the obtained Fe-BTC showed excellent capacities and adsorption rates for different adsorbates. Besides the general adsorption effect derived from the numerous pores and large specific surface area, the electrostatic forces and π-π interactions between benzene rings are believed to play significant roles in the large uptakes of this Fe-BTC sample. And the existence of mesopores in Fe-BTC might accelerate the adsorption.

Key words: One-pot synthesis, Metal-organic framework, Water purification, Adsorption

HAN Qian, WANG Zumin, CHEN Xiaoyu, JIAO Chuangwei, LI Haiyan, YU Ranbo. Facile Synthesis of Fe-b ased MOFs(Fe-BTC) as Efficient Adsorbent for Water Purifications[J]. Chemical Research in Chinese Universities, 2019, 35(4): 564-569.

References 32

[1]	Ahmaruzzaman M., Advanced Colloid Interface Science, 2008, 143(1), 48
[2]	Herbst A., Janiak C., CrystEngComm, 2017, 19(29), 4092
[3]	Cao X., Tan C., Sindoro M., Zhang H., Chemical Society Reviews, 2017, 46(10), 2660
[4]	Wu M. X., Yang Y. W., Advanced Materials, 2017, 29(23), 1606134
[5]	Peng Y., Huang H., Zhang Y., Kang C., Chen S., Song L., Liu D., Zhong C., Nature Communications, 2018, 9(1), 187
[6]	Dias E. M., Petit C., Journal of Materials Chemistry A, 2015, 3(45), 22484
[7]	Li J., Wang X., Zhao G., Chen C., Chai Z., Alsaedi A., Hayat T., Wang X., Chemical Society Reviews, 2018, 47(7), 2322
[8]	Zhang F., Shi J., Jin Y., Fu Y., Zhong Y., Zhu W., Chemical Engineering Journal, 2015, 259, 183
[9]	Liu C., Yu L., Zhao Y., Lv Y., Microchimica Acta, 2018, 185(7), 342
[10]	Seo Y., Yoon J. W., Lee J. S., Hwang Y. K., Jun C., Chang J., Wuttke S., Bazin P., Vimont A., Daturi M., Bourrelly S., Llewellyn P. L., Horcajada P., Serre C., Férey G., Advanced Materials, 2012, 24(6), 806
[11]	Ma J., Kalenak A. P., Wong-Foy A. G., Matzger A. J., AngewandteChemie, 2017, 129(46), 14810
[12]	Lv Y., Zhan W., He Y., Wang Y., Kong X., Kuang Q., Xie Z., Zheng L., ACS Applied Materials &Interfaces, 2014, 6(6), 4186
[13]	Wang Z., Gu L., Song L., Wang H., Yu R., Materials Chemistry Frontiers, 2018, 2(5), 1024
[14]	Ramos-Fernández E. V., Grau-Atienza A., Farrusseng D., Aguado S., Journal of Materials Chemistry A, 2018, 6(14), 5598
[15]	Dhakshinamoorthy A., Alvaro M., Garcia H., Catalysis Communications, 2017, 97, 74
[16]	Génin J. M. R., Olowe A. A., Refait P., Simon L., Corrosion Science, 1996, 38(10), 1751
[17]	Yang Y., Bai Y., Zhao F., Yao E., Yi J., Xuan C., Chen S., RSC Advances, 2016, 6(71), 67308
[18]	Zhu B., Yu X., Jia Y., Peng F., Sun B., Zhang M., LuoT., Liu J., Huang X., Journal of Physical Chemistry C, 2012, 116(116), 8601
[19]	Jonge H., Mittelmeijerhazeleger M., Environmental Science & Technology, 1996, 30(12), 3634
[20]	Horcajada P., Surblé S., Serre C., Hong D., Seo Y. K., Chang J., Grenèche J., Margiolaki I., Féreya G., Chemical Communications, 2007, 27(27), 2820
[21]	Yamashita T., Hayes P., Applied Surface Science, 2008, 254(8), 2441
[22]	Liu H., Wang Z., Li H., Wang H., Yu R., Materials Research Bulletin, 2018, 100(1), 302
[23]	Haque E., Jun J., Jhung S., Journal of Hazardous Materials, 2011, 185(1), 507
[24]	Desai A. V., Manna B., Karmakar A., Sahu A., Ghosh S. K., AngewandteChemie, 2016, 128(27), 7942
[25]	Ho K. Y., Gordon Mckay A., Yeung K. L., MRS Online Proceedings Library Archive, 2003, 788(7), 3019
[26]	Wang X. S., Liang J., Li L., Lin Z. J., Bag P. P., Gao S. Y., Huang Y., Cao R., Inorganic Chemistry, 2016, 55(5), 2641
[27]	Jia Y., Jin Q., Li Y., Sun Y., Huo J., Zhao X., Analytical Methods, 2014, (4), 1463
[28]	Tong M., Liu D., Yang Q., Devautour-Vinot S., Maurin G., Zhong C., Journal of Materials Chemistry A, 2013, 1(30), 8534
[29]	Cordova K. E., Yaghi O. M., Materials Chemistry Frontier, 2017, 1(7), 1304
[30]	Guo Y., Zhao J., Zhang H., Yang S., Qi J., Wang Z., Xu H., Dyes & Pigments, 2005, 66(2), 123
[31]	Pelekani C., Snoeyink V. L., Carbon, 2001, 39(1), 25
[32]	Debabrata M., Soumita M., Parukuttyamma S. D., ACS Sustainable Chemistry & Engineering, 2017, 5(12), 11255

Facile Synthesis of Fe-b ased MOFs(Fe-BTC) as Efficient Adsorbent for Water Purifications

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