Synthesis and Herbicidal Activity of Novel Sulfonylureas Containing 1,2,4-Triazolinone Moiety

doi:10.1007/s40242-013-2377-3

Chemical Research in Chinese Universities ›› 2013, Vol. 29 ›› Issue (3): 466-472.doi: 10.1007/s40242-013-2377-3

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Synthesis and Herbicidal Activity of Novel Sulfonylureas Containing 1,2,4-Triazolinone Moiety

LIU Zhuo, PAN Li, LI Yong-hong, WANG Su-hua, LI Zheng-ming

State Key Laboratory of Elemento-Organic Chemistry, Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, P. R. China

Received:2012-10-09 Revised:2012-11-04 Online:2013-06-01 Published:2013-05-15
Contact: Zheng-ming LI E-mail:nkzml@vip.163.com
Supported by:
Supported by the National Basic Research Program of China(No.2010CB126106), the National Natural Science Foundation of China(No.21272129) and the National Key Technologies R&D Program, China(No.2011BAE06B05).

Abstract

Abstract:

A series of new sulfonylureas incorporating 1,2,4-triazolinone moiety was synthesized, which were further bio-assayed for the herbicidal activity against four herbs, representative of monocotyledons and dicotyledons. Some of them exhibited high potency to inhibit the growth of dicotyledons(Bassica napus and Amaranthus retroflexus) in the pot experiment. Compounds 9a and 9b also displayed an excellent herbicidal activity against Bassica napus at a concentration of 15 g/hectare, which were comparable with commercial triasulfuron.

Key words: Sulfonylurea herbicide, Acetohydroxyacid synthetase(AHAS), 1,2,4-Triazolinone derivative, Protox, Herbicidal activity

LIU Zhuo, PAN Li, LI Yong-hong, WANG Su-hua, LI Zheng-ming. Synthesis and Herbicidal Activity of Novel Sulfonylureas Containing 1,2,4-Triazolinone Moiety[J]. Chemical Research in Chinese Universities, 2013, 29(3): 466-472.

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Synthesis and Herbicidal Activity of Novel Sulfonylureas Containing 1,2,4-Triazolinone Moiety

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