Sequential Extraction of Natural Surface Coatings: Comparison with Single Stage Extraction and Its Application in Investigating Adsorption Characteristics of Surface Coating Components for Metals

Abstract

Abstract: Multistage sequential extraction with different sequences was applied to extracting natural surface coatings( NSCs), and the results were compared with those by single stage extraction technique. The optimal sequential extraction scheme with the best performance was selected and incorporated into the method of selective extraction followed by adsorption and statistic analyses to study the adsorption parameters of Fe oxides, Mn oxides and organic matters in NSCs for Pb and Cd, to validate the applicability of the sequential extraction scheme. The Langmuir adsorption parameters of each component of surface coating estimated according to the adsorption data of single stage extraction of NSCs were all similar to those of sequential extraction of NSCs, and the maximum difference between the metal adsorption abilities of the components estimated via the two extraction techniques was only about 20%, indicating that either extraction techniques could be used. The optimal sequential extraction scheme obtained was first extracted with NH₂OH·HCl, then with Na₂S₂O₄, and finally with oxalic acid.

Key words: Natural surface coating(NSC), Sequential extraction, Single stage extraction, Adsorption, Component

HUA Xiu-yi, LIU Xiao-xue, DONG De-ming, LI Ming, LI Yao-rui. Sequential Extraction of Natural Surface Coatings: Comparison with Single Stage Extraction and Its Application in Investigating Adsorption Characteristics of Surface Coating Components for Metals[J]. Chemical Research in Chinese Universities, 2012, 28(1): 41-46.

References

[1] Stumm W., Morgan J. J., Aquatic Chemistry: Chemical Equilibriaand Rates in Natural Waters, Wiley, New York, 1996, 516 [2] Lion L. W., Shuler M. L., Ghiorse W. C., CRC Crit. Rev. Environ.Control, 1988, 17, 273 [3] Segura R., Arancibia V., Zuniga M. C., Pasten P., J. Geochem. Explor.,2006, 91, 71 [4] Dong D. M., Nelson Y. M., Lion M. L., Ghiorse W. C., Water Res.,2000, 34, 427 [5] Dong D. M., Zhao X. M., Hua X. Y., Zhang J. J., Wu S. M., Chem.Res. Chinese Universities, 2007, 23(6), 659 [6] Costerton J. W., Chen K. J., Geesey G. G., Ladd T. L., Nickel J. C.,Dasguta M., Marrie T. J., Annu. Rev. Microbiol., 1987, 41, 435 [7] Guo Z. Y., Hua X. Y., Liang D. P., Dong D. M., Li M., Li Y. T., SongX., Lin H. Y., Chem. J. Chinese Universities, 2010, 31(5), 919 [8] Ballance S., Phillips P. J., McCrohan C. R., Powell J. J.,Jugdaohsingh R., White K. N., Can. J. Fish. Sci., 2001, 58, 1708 [9] Nelson Y. M., Lion L. M., Shuler M. L., Ghiorse W. C., Limnol.Oceanogr., 1999, 44, 1715 [10] Dong D. M., Hua X. Y., Li Y., Kang C. L., Chem. J. ChineseUniversities, 2002, 23(2), 294 [11] Dong D. M., Hua X. Y., Li Y., Zhang J. J., Yan D. X., Environ. Sci.Technol., 2003, 37, 4106 [12] Tessier A., Campbell P. G. C., Bisson M., Anal. Chem., 1979, 51, 844 [13] Kheboian C., Bauer C. F., Anal. Chem., 1987, 59, 1417 [14] Rao C. R. M., Sahuquillo A., Lopez-Sanchez J. F., Anal. Chim. Acta,2010, 662, 128 [15] Young L. B., Dutton M., Pick F. R., Biogeochemistry, 1992, 17, 205 [16] Gleyzes C., Tellier S., Astruc M., Trends Anal. Chem., 2002, 21, 451 [17] Nemati K., Abu Bakar N. K., Bin Abas M. R., Sobhanzadeh E., Low K. H., Environ. Monit. Assess., 2011, 176, 313 [18] Martin J. M., Nirel P., Thomas A. G., Mar. Chem., 1987, 22, 313 [19] Passos E. A., Alves J. C., Santos I. S., dos Alves J. P. H., Garcia C. A.B., Costa A. C. S., Microchem. J., 2010, 96, 50 [20] Hua X. Y., Dong D. M., Fei S., Zheng N., Li Y., Environ. Chem.,2005, 24, 669 [21] Dong D. M., Liu L., Hua X. Y., Lu Y. Z., Microchem. J., 2007, 85,270 [22] Dong D. M., Li Y., Zhang B. Y., Hua X. Y., Yue B. H., Microchem. J.,2001, 69, 89 [23] Coffin D. E., Can. J. Soil Sci., 1963, 43, 7 [24] Anderson B. J., Jenne E. A., Soil. Sci., 1970, 109, 163 [25] McKeague J. A., Day J. H., Can. J. Soil Sci., 1966, 46, 13 [26] Mitchell B. D., Farmer V. C., McHardy W. J., Adv. Agron., 1964, 16,327 [27] Miller W. P., Martens D. C., Zelazny L. W., Soil Sci. Soc. Am. J.,1986, 50, 591 [28] Heron J. G., Crouzet C., Bourg A. C. M., Christensen T. H., Environ.Sci. Technol., 1994, 28, 1698