Estimation of Critical Rate of Temperature Rise for Thermal Explosion of First Order Autocatalytic Decomposition Reaction Systems by Using Non-isothermal DSC

Chemical Research in Chinese Universities ›› 2004, Vol. 20 ›› Issue (2): 163-165.

• Articles • Previous Articles Next Articles

Estimation of Critical Rate of Temperature Rise for Thermal Explosion of First Order Autocatalytic Decomposition Reaction Systems by Using Non-isothermal DSC

GUO Peng-jiang^1,2, HU Rong-zu^1,3, ZHANG Hai^1,2, XIA Zhi-ming^1,2, SONG Ji-rong¹, GAO Sheng-li¹, NING Bin-ke³, SHI Qi-zhen¹, LIU Rong⁴, LU Gui-e⁵, JIANG Ji-you⁵

1. Shaanxi Key Laboratory of Physico-Inorganic Chemistry and Department of Chemistry;
2. Department of Mathematics, Northwest University, Xi′an 710069, P. R. China;
3. Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China;
4. Department of Food Engineering, Nanchang University, Nanchang 330047, P. R. China;
5. Ordnance Engineering Institute, Shijiazhuang, 050000, P. R. China

Received:2003-05-06 Online:2004-04-24 Published:2011-08-06
Supported by:
Supported by the Science and Technology Foundation of Shaanxi Key Laboratory of Physico-Inorganic Chemistry(No.29-3, 2001) and the Science and Technology Foundation of Propellant and Explosive Combustion of China(No.514550101).

Abstract

Abstract: A method of estimating the critical rate of temperature rise for the thermal explosion of first order autocatalytic decomposition reaction systems by using non-isothermal DSC is presented. The information was obtained on the increasing rate of temperature for the first order autocatalytic decomposition of nitrocellulose containing 13.86% nitrogen converting into the thermal explosion.

Key words: DSC, Critical rate of temperature rise, NC, Non-isothermal change, Thermal explosion

GUO Peng-jiang, HU Rong-zu, ZHANG Hai, XIA Zhi-ming, SONG Ji-rong, GAO Sheng-li, NING Bin-ke, SHI Qi-zhen, LIU Rong, LU Gui-e, JIANG Ji-you. Estimation of Critical Rate of Temperature Rise for Thermal Explosion of First Order Autocatalytic Decomposition Reaction Systems by Using Non-isothermal DSC[J]. Chemical Research in Chinese Universities, 2004, 20(2): 163-165.

[1]	ZHENG Meng, WANG Jin. Regulating the Oxygen Affinity of Single Atom Catalysts by Dual-atom Design for Enhanced Oxygen Reduction Reaction Activity [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1275-1281.
[2]	ZHANG Xinyu, TANG Pengpeng, ZHAI Guangyao, LIN Xiu, ZHANG Qiang, CHEN Jiesheng, WEI Xiao. Regulating Phase Junction and Oxygen Vacancies of TiO₂ Nanoarrays for Boosted Photoelectrochemical Water Oxidation [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1292-1300.
[3]	HE Lulu, CHEN Xin, REN Yuanhang, YUE Bin, TSANG Shik Chi Edman, HE Heyong. Improving Catalytic Stability and Coke Resistance of Ni/Al₂O₃ Catalysts with Ce Promoter for Relatively Low Temperature Dry Reforming of Methane Reaction [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1032-1040.
[4]	SONG Weiyu, LV Xintong, GAO Yang, WANG Lu. Photocatalytic HER Performance of TiO₂-supported Single Atom Catalyst Based on Electronic Regulation:A DFT Study [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1025-1031.
[5]	XIAO Chulei, CHI Quan, WANG Xian. Recent Progress in Mass Spectrometry-based Metabolomics for Colorectal Cancer [J]. Chemical Research in Chinese Universities, 2022, 38(4): 886-893.
[6]	TU Tingting, HUAN Shuangyan, KE Guoliang, ZHANG Xiaobing. Functional Xeno Nucleic Acids for Biomedical Application [J]. Chemical Research in Chinese Universities, 2022, 38(4): 912-918.
[7]	HUANG Qin, LIU Xin, ZHANG Pengge, WU Zhan, ZHAO Zilong. A DNA Nano-train Carrying a Predefined Drug Combination for Cancer Therapy [J]. Chemical Research in Chinese Universities, 2022, 38(4): 928-934.
[8]	CHEN Minwen, LIAO Tao, ZENG Linsheng, ZENG Zhongyi, YANG Qinglai, WANG Guoxin. Plasmonic Gold Chip for Multiplexed Detection of Ovarian Cancer Biomarker in Urine [J]. Chemical Research in Chinese Universities, 2022, 38(4): 935-940.
[9]	YANG Zhichen, KANG Xiaoting, ZOU Bo, YUAN Xuna, LI Yajie, WU Qin, GUO Yupeng. Development of the Self-doping Porous Carbon and Its Application in Supercapacitor Electrode [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1065-1072.
[10]	WANG Yue, WANG Jinling, MA Jianxin, ZHANG Yue, XU Na, WANG Xiuli. Multi-functional Photoelectric Sensor Based on a Three-fold Interpenetrated Cd(II) Coordination Polymer for Sensitively Detecting Different Ions [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1105-1110.
[11]	ZHANG Bingyi, ZHANG Xiaolei, SU Ruochen, SUN Yue and DUAN Lian. ESIPT-regulated Mechanoresponsive Luminescence Process by Introducing Intramolecular Hydrogen Bond in Naphthalimide Derivatives#br# [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1050-1056.
[12]	CHEN Zhangwu and LI Fen. Proton-induced Conversion from Non-Aufbau to Aufbau Electronic Structure of an Organic Radical with Turn-on Fluorescence [J]. Chemical Research in Chinese Universities, 2022, 38(3): 798-802.
[13]	HU Shifan, WANG Yafeng and SU Bin. Effect of Ionic Strength on the Electrochemiluminescence Generation by Tris(2,2'-bipyridyl)ruthenium(II)/Tri-n-propylamine [J]. Chemical Research in Chinese Universities, 2022, 38(3): 816-822.
[14]	ZHAO Lili, GONG Zhou, ZHAO Qun, ZHANG Lihua, and ZHANG Yukui. Deciphering In-vivo Cross-linking Mass Spectrometry Data for Dynamic Protein Structure Analysis [J]. Chemical Research in Chinese Universities, 2022, 38(3): 758-762.
[15]	LUO Zha, LIU Hao, SHEN Wei, SHI Kun, CHEN Ankang, SHENG Libo, SUI Yongming and ZOU Bo. Effects of High Pressure on the Surface Plasmon Resonance of Copper and Silver Nanocrystals [J]. Chemical Research in Chinese Universities, 2022, 38(3): 843-846.

Estimation of Critical Rate of Temperature Rise for Thermal Explosion of First Order Autocatalytic Decomposition Reaction Systems by Using Non-isothermal DSC

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments