Assembly and Characterization of Rare-earth-containing Polyoxometalate [Eu(P2Mo17O61)2]17- and Poly(allylamine hydrochloride) Multilayer Films

Chemical Research in Chinese Universities ›› 2004, Vol. 20 ›› Issue (1): 15-19.

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Assembly and Characterization of Rare-earth-containing Polyoxometalate [Eu(P₂Mo₁₇O₆₁)₂]^17- and Poly(allylamine hydrochloride) Multilayer Films

JIANG Min¹, ZHANG Hong¹, WANG En-bo¹, KANG Zhen-hui¹, LIAN Suo-yuan¹, XU Lin¹, WU Ai-guo², LI Zhuang²

1. Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China;
2. State Key Laboratory of Electroanalytical Chemistry, Changchun 4Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China

Received:2002-11-11 Online:2004-02-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.20171010).

Abstract

Abstract: The ultrathin multilayer films of rare-earth-containing polyoxometalate cluster K₁₇[Eu(P₂Mo₁₇O₆₁)₂](EuPMo) and poly(allylamine hydrochloride)(PAH) have been prepared by the Layer-by-Layer(LbL) self-assembly method. The photoluminescent behavior of the films investigated at room temperature shows the Eu³⁺ characteristic emission pattern of ⁵D₀→⁷F_J(J=1-4). The occurrence of the photoluminescent activity confirms the potential of creating luminescent multilayer films with polyoxometalates(POMs).

Key words: Polyoxometalate, Layer-by-Layer, Multilayer film, Luminescence

JIANG Min, ZHANG Hong, WANG En-bo, KANG Zhen-hui, LIAN Suo-yuan, XU Lin, WU Ai-guo, LI Zhuang. Assembly and Characterization of Rare-earth-containing Polyoxometalate [Eu(P₂Mo₁₇O₆₁)₂]^17- and Poly(allylamine hydrochloride) Multilayer Films[J]. Chemical Research in Chinese Universities, 2004, 20(1): 15-19.

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Assembly and Characterization of Rare-earth-containing Polyoxometalate [Eu(P₂Mo₁₇O₆₁)₂]^17- and Poly(allylamine hydrochloride) Multilayer Films

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