Direct Immobilization of Phosphine-Rhodium Complex on MCM-41 for Propene Hydroformylation

Chemical Research in Chinese Universities ›› 2002, Vol. 18 ›› Issue (3): 311-315.

• Articles • Previous Articles Next Articles

Direct Immobilization of Phosphine-Rhodium Complex on MCM-41 for Propene Hydroformylation

CAI Yang, LI Zhi-hua, YANG Yi-quan, YUAN You-zhu

State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen 361005, P. R. China

Received:2001-07-02 Online:2002-08-24 Published:2011-08-04
Supported by:
Supported by the National Natural Science Foundation of China(Nos. 29873037, 20023001 and 20021002), State Key Project for Fundamental Research(No.G200004808) and the Ministry of Education of China.

Abstract

Abstract: MCM-41 molecular sieve supported Rh-PPH₃ catalysts were prepared by the in-situ assembling of the metal complex from smaller moieties of Rh(acac)(CO)₂ and ligand of PPH₃. The resulted guest/host materials(Rh-PPH₃/MCM-41) were characterized by X-ray powder diffraction, FTIR and ³¹P(¹H) NMR, and served as catalysts for propene hydroformylation. The results showed negligible change in MCM-41 framework after propene hydroformylation at 393 K. Higher hydroformylation activities were obtained on Rh-PPH₃/MCM-41 catalysts compared to that on Rh-PPH₃/SiO₂.

Key words: MCM-41 mesoporous molecular sieve, Hydroformylation, Propene, Rh-phopshine complex

CAI Yang, LI Zhi-hua, YANG Yi-quan, YUAN You-zhu. Direct Immobilization of Phosphine-Rhodium Complex on MCM-41 for Propene Hydroformylation[J]. Chemical Research in Chinese Universities, 2002, 18(3): 311-315.

[1]	SONG Lili, CHEN Chao, CHEN Xiangbin, ZHANG Ning. Basic Catalytic Performance of Amino and Acylamide Functionalized Metal-organic Framework in the Synthesis of Chloropropene Carbonate from CO₂ Under Atmospheric Pressure [J]. Chemical Research in Chinese Universities, 2016, 32(5): 838-842.
[2]	SHI Yukun, HU Xiaojing, ZHU Baolin, ZHANG Shoumin, HUANG Weiping. Hydroformylation of 1-Octene over Nanotubular TiO₂-supported Amorphous Co-B Catalysts [J]. Chemical Research in Chinese Universities, 2015, 31(5): 851-857.
[3]	WU Nan-nan, LIU Hong-xia, DUAN Xue-mei, LIU Jing-yao. Theoretical Study of CH₃CH=CH₂+O(¹D) Reaction: Mechanism and Kinetics [J]. Chemical Research in Chinese Universities, 2012, 28(1): 147-152.
[4]	LI Xian-ming, DING Yun-jie*, JIAO Gui-ping, LI Jing-wei, YAN Li and ZHU He-jun. Phosphite Ligand Modified Supported Rhodium Catalyst for Hydroformylation of Internal Olefins to Linear Aldehydes [J]. Chemical Research in Chinese Universities, 2009, 25(5): 738-739.
[5]	WEI Chang-ping, LI Shu-zeng, ZHOU Bin, PENG Chun-jia, ZHEN Kai-ji. Catalytic Synthesis of Isopropyl Benzene over SO₄^2-/ZrO₂-MCM-41 [J]. Chemical Research in Chinese Universities, 2006, 22(3): 371-374.
[6]	LEI Ming, FENG Wen-lin, XU Zhen-feng . Ab Initio MO Studies on the Reaction Mechanism for Carbonyl Insertion Catalyzed by Carbonyl Cobalt Complex [J]. Chemical Research in Chinese Universities, 2000, 16(1): 31-35.
[7]	ZHU Fang-ming, WU Qing, FANG YU-tang, HUANG Qun-fang, LIN Shang-an . Synthesis of Syndiotactic Polystyrene/Atactic Polypropene Block Copolymer in the presnece of Half-sandwich Titanocene Catalysts [J]. Chemical Research in Chinese Universities, 2000, 16(1): 83-89.
[8]	MA Jun, SHEN Jian-ping, SUN Tie, JIANG Da-zhen. Alkylation of Benzene with Propene over Hβ Zeolite──The Effect of Reaction Conditionson the Distribution of Products [J]. Chemical Research in Chinese Universities, 1995, 11(1): 39-44.
[9]	He Binglin(Ho PingLum), Sun Juntan, Li Hong, Sang Junjie, Zhao Fenzhi. Synthesis of Polymer-Supported Heteronuclear Rhodium-Cobalt Bimetallic Carbonyl Cluster Catalysts and Their Hydroformylation Properties [J]. Chemical Research in Chinese Universities, 1989, 5(4): 357-362.

Direct Immobilization of Phosphine-Rhodium Complex on MCM-41 for Propene Hydroformylation

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 9

Recommended Articles

Metrics

Comments