Hydroformylation of 1-Octene over Nanotubular TiO2-supported Amorphous Co-B Catalysts

doi:10.1007/s40242-015-5002-9

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (5): 851-857.doi: 10.1007/s40242-015-5002-9

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Hydroformylation of 1-Octene over Nanotubular TiO₂-supported Amorphous Co-B Catalysts

SHI Yukun, HU Xiaojing, ZHU Baolin, ZHANG Shoumin, HUANG Weiping

Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, The Key Laboratory of Advanced Energy Materials Chemistry, Ministry of Education, Tianjin Key Lab of Metal and Molecule-based Material Chemistry, Nankai University, Tianjin 300071, P. R. China

Received:2015-01-04 Revised:2015-04-03 Online:2015-10-01 Published:2015-05-18
Contact: HUANG Weiping, E-mail: hwp914@nankai.edu.cn E-mail:hwp914@nankai.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21373120, 21301098, 21071086, 21271110), the National "111" Project of China's Higher Education(No.B12015), the Applied Basic Research Programs of Science and Technology Commission Foundation of Tianjin, China(Nos.13JCQNJC02000, 12JCYBJC13100).

Abstract

Abstract:

TiO₂ nanotubes supported amorphous Co-B(Co-B/TNTs) catalyst was prepared via impregnationchemical reduction procedure. The catalyst was characterized with transmission electron microscopy(TEM), ammonia temperature-programmed desorption(NH₃-TPD), thermogravimetry-differential thermal analysis(TG-DTA), Fourier transform infrared spectroscopy(FTIR) and Raman spectroscopy. The effects of temperature and ratio of CO to H₂ on the hydroformylation of 1-octene were studied. At an optimized reaction temperature(150℃) and volume ratio of CO to H₂(2:1), the conversion of 1-octene can reach 97.4% with a selectivity of 23.1% for total aldehydes and n/i-aldehyde molar ratio of 40:60. To obtain higher selectivity for linear aldehydes, Co-B/TNTs modified with triphenylphosphine for the hydroformylation of 1-octene were investigated. When molar ratio of P/Co was 4, the yield of total aldehydes was the highest(31.6%) with a good selectivity for linear product(n/i-aldehyde molar ratio was 70:30). In recycle use, the Co-B/TNTs catalyst modified with triphenylphosphine could be reused five times without reducing the activity and selectivity obviously. For a comparative study, all the Co-B/TNTs to catalyze the hydroformylation of other olefins exhibited high conversion under the optimized conditions.

Key words: Hydroformylation, TiO₂ nanotubes, Amorphous Co-B, 1-Octene

SHI Yukun, HU Xiaojing, ZHU Baolin, ZHANG Shoumin, HUANG Weiping. Hydroformylation of 1-Octene over Nanotubular TiO₂-supported Amorphous Co-B Catalysts[J]. Chemical Research in Chinese Universities, 2015, 31(5): 851-857.

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Hydroformylation of 1-Octene over Nanotubular TiO₂-supported Amorphous Co-B Catalysts

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