[H2dab][GaB5O10]: an Acentric Galloborate with a 4-Connected Uninodal Framework

doi:10.1007/s40242-024-4130-5

Abstract

Abstract: A new acentric galloborate (GBO) [H₂dab][GaB₅O₁₀] (1, 1,4-dab: 1,4-diaminobutane) has been synthesized under solvothermal conditions. The alternation of 4,4-connected GaO₄ and B₅O₁₀ cluster build up the 3D [GaB₅O₁₀]_n^2n‒ uninodal framework, which contains three pairs of helical channels with 8-member ring (MR) and 7-MR apertures, respectively. Compound 1 exhibits a moderate second harmonic generation (SHG) response of 1.8 times that of KH₂PO₄ (KDP), indicating its potential application in UV regions. The acentric uninodal framework in compound 1 represents a new type of zeolitic framework in the GBOs’ family.

Key words: Galloborate, Solvothermal synthesis, Nonlinear optics, Zeolitic framework

LIU Wenfang, CHEN Chongan, YANG Guoyu. [H₂dab][GaB₅O₁₀]: an Acentric Galloborate with a 4-Connected Uninodal Framework[J]. Chemical Research in Chinese Universities, 2024, 40(4): 747-752.

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[H₂dab][GaB₅O₁₀]: an Acentric Galloborate with a 4-Connected Uninodal Framework

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