Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO2

doi:10.1007/s40242-023-3165-3

Abstract

Abstract: Two bio-based seven-membered cyclic carbonate monomers M1 and M2 were synthesized in three steps from myrcene, which could produce polycarbonates via ring-opening polymerization using metal or organic catalysts. The functionalizable olefin moieties in resulting polycarbonates have driven post-polymerization modifications via radical cross-linking and hydrogenation, enabling the resulting polymers with tunable thermal properties. More importantly, the chemical recycling of P(M)s was achieved through "monomer → polymer ⇄ dimer", which presented a platform for the synthesis of chemically recyclable biobased polycarbonates.

Key words: Biomass, CO₂, Polycarbonate, Functionalization, Chemical recyclability

WU Yanchen, FAN Huazhong, SHAN Siyi, WANG Siqi, CAI Zhongzheng, ZHU Jian-Bo. Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO₂[J]. Chemical Research in Chinese Universities, 2023, 39(5): 809-815.

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Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO₂

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