Remarkably Enhanced Hydrogen Oxidation Reaction Activity of Carbon-supported Pt by Facile Nickel Modification

doi:10.1007/s40242-020-9074-9

Chemical Research in Chinese Universities ›› 2020, Vol. 36 ›› Issue (1): 105-109.doi: 10.1007/s40242-020-9074-9

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Remarkably Enhanced Hydrogen Oxidation Reaction Activity of Carbon-supported Pt by Facile Nickel Modification

HUANG Xuewei^1,2, LONG Chang^2,3, HAN Jianyu², ZHANG Jing^2,4, QIU Xueying^2,3, TANG Zhiyong^1,2

1. College of Chemistry, Zhengzhou University, Zhengzhou 450001, P. R. China;
2. CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, P. R. China;
3. School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150080, P. R. China;
4. Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, P. R. China

Received:2019-11-30 Revised:2020-01-02 Online:2020-02-01 Published:2020-01-02
Contact: TANG Zhiyong E-mail:zytang@nanoctr.cn
Supported by:
Supported by the National Key Basic Research Program of China(No.2016YFA0200700), the National Natural Science Foundation of China(Nos.21890381, 21721002), the Frontier Science Key Project of Chinese Academy of Sciences (No.QYZDJ-SSW-SLH038) and the K. C. Wong Education Foundation.

Abstract

Abstract: Developing high activity catalysts for hydrogen oxidation reaction(HOR) under alkaline condition remains a challenge in the exchange membrane fuel cell(AEMFC). Herein, we report that the activity of carbon-supported platinum(Pt/C) towards the hydrogen oxidation reaction(HOR) in alkaline media can be remarkably enhanced by simple immersion of Pt/C in nickel chloride solution. The adsorption of hydrogen on the catalyst surface is weakened by modification of nickel. The HOR activity on the Pt/C after immersion possesses an excellent mass current density of 33.4 A/g_metal, which is 18% higher than that(28.3 A/g_metal) on Pt/C.

Key words: Electrocatalyst, Hydrogen oxidation, Pt/C, Modified nickel

HUANG Xuewei, LONG Chang, HAN Jianyu, ZHANG Jing, QIU Xueying, TANG Zhiyong. Remarkably Enhanced Hydrogen Oxidation Reaction Activity of Carbon-supported Pt by Facile Nickel Modification[J]. Chemical Research in Chinese Universities, 2020, 36(1): 105-109.

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Remarkably Enhanced Hydrogen Oxidation Reaction Activity of Carbon-supported Pt by Facile Nickel Modification

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