Copper-linked 1T MoS2/Cu2O Heterostructure for Efficient Photocatalytic Hydrogen Evolution

doi:10.1007/s40242-020-0319-4

Chemical Research in Chinese Universities ›› 2020, Vol. 36 ›› Issue (6): 1122-1127.doi: 10.1007/s40242-020-0319-4

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Copper-linked 1T MoS₂/Cu₂O Heterostructure for Efficient Photocatalytic Hydrogen Evolution

YIN Yage¹, WEI Shuting¹, ZHANG Lei^1,2, GUO Ziwang¹, HUANG Haihua¹, SAI Shiran¹, WU Jiandong¹, XU Yanchao¹, LIU Ying¹, ZHENG Lirong³, FAN Xiaofeng¹, CUI Xiaoqiang¹

1. Key Laboratory of Automobile Materials of Ministry of Education and School of Materials Science and Engineering, Jilin University, Changchun 130012, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
3. Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2020-10-06 Revised:2020-11-04 Online:2020-12-01 Published:2020-12-03
Contact: ZHANG Lei, CUI Xiaoqiang E-mail:xqcui@jlu.edu.cn;lzhang@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.51872116, 12034002), the National Key Research and Development Program of China(No.2016YFA0200400), the Fundamental Research Funds for the Central Universities of China, the Science and Technology Development Program of Jilin Province, China(No.20190201233JC) and the Program for JLU Science and Technology Innovative Rsearch Team, China(No.JLUSTIRT2017TD-09).

Abstract

Abstract: Metallic 1T phase molybdenum disulfide(1T MoS₂) is an excellent catalyst due to the abundant active sites and good conductivity. However, complex synthesis and unstable nature of 1T MoS₂ still limit its practical application. Herein, we propose a simple method to trigger the phase transition of MoS₂. This phase transition is first predicted by density functional theory(DFT) calculations and then confirmed by Raman spectroscopy and high-resolution transmission electron microscopy(HRTEM). 1T MoS₂/Cu₂O heterostructure catalyst is then developed, showing enhanced photocatalytic hydrogen evolution.

Key words: Photocatalysis, Hydrogen evolution, Phase transition, Heterostructure

YIN Yage, WEI Shuting, ZHANG Lei, GUO Ziwang, HUANG Haihua, SAI Shiran, WU Jiandong, XU Yanchao, LIU Ying, ZHENG Lirong, FAN Xiaofeng, CUI Xiaoqiang. Copper-linked 1T MoS₂/Cu₂O Heterostructure for Efficient Photocatalytic Hydrogen Evolution[J]. Chemical Research in Chinese Universities, 2020, 36(6): 1122-1127.

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Copper-linked 1T MoS₂/Cu₂O Heterostructure for Efficient Photocatalytic Hydrogen Evolution

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