Synergistic Inhibition Effect of Sodium Silicate and Acrylamide on the Corrosion of Carbon Steel in a High-concentration KCl Solution

doi:10.1007/s40242-017-6286-8

Chemical Research in Chinese Universities ›› 2017, Vol. 33 ›› Issue (1): 100-106.doi: 10.1007/s40242-017-6286-8

• Articles • Previous Articles Next Articles

Synergistic Inhibition Effect of Sodium Silicate and Acrylamide on the Corrosion of Carbon Steel in a High-concentration KCl Solution

ZHAO Jingmao^1,2, ZHANG Manlu¹, TIE Zhiwei¹

1. College of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China;
2. Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received:2016-07-05 Revised:2016-09-20 Online:2017-02-01 Published:2016-12-05
Contact: ZHAO Jingmao,E-mail:zhaojm1@mail.buct.edu.cn E-mail:zhaojm1@mail.buct.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.51471021).

Abstract

Abstract:

The corrosion inhibition performances of sodium silicate(Na₂SiO₃) and acrylamide(AM) for Q235 carbon steel in a high-concentration KCl solution(25%, mass fraction) were investigated via static mass loss method, electrochemical measurements, scanning electron microscopy(SEM), X-ray photoelectron spectroscopy(XPS) and Auger electron spectroscopy(AES). AM shows poor inhibition performance, while Na₂SiO₃ exhibits a better inhibition performance. Moreover, the steel gains mass instead of losing mass in the presence of 0.5% Na₂SiO₃ and 0.5% AM, indicating that the corrosion is completely inhibited. SEM analysis indicates that a compact protective film is formed on the steel surface by the combined use of inhibitors. Our results demonstrate that Na₂SiO₃ and AM could have a synergistic effect on steel corrosion in high concentrations of KCl. The synergistic inhibition mechanism is further conjectured by the XPS and AES analysis.

Key words: KCl solution, Sodium silicate, Acrylamide, synergistic inhibition effect, Corrosion inhibitor

ZHAO Jingmao, ZHANG Manlu, TIE Zhiwei. Synergistic Inhibition Effect of Sodium Silicate and Acrylamide on the Corrosion of Carbon Steel in a High-concentration KCl Solution[J]. Chemical Research in Chinese Universities, 2017, 33(1): 100-106.

References

[1] Liu P. D., Liu C. H., Liao S. M., Wu X. Z., Yue H., Wu X. Z., Xiong J. Y., Nat. Gas Ind., 2005, 25(4), 83
[2] Cai L., The Research and Application of Environmentally Friendly Completion Fluid, Daqing Pet. Inst., Daqing, 2009
[3] Zheng J. S., Lv Z. P., Tang Y., Peng F. M., Corros. Prot., 1997, (5), 7
[4] Liu F. G., The Study of Corrosion Mechanism of Drill Pipe and Pipeline, Inhibition and Mechanism of the Inhibitor for Drill Pipe and Pipeline, Ocean Univ. China, Qingdao, 2008
[5] Yuan M. R., Lu J. T., Kong G., Surf., Coat. Technol., 2010, 204(8), 1229
[6] Lin B. L., Lu G. T., Kong G., Surf., Coat. Technol., 2008, 202(9), 1831
[7] Gao H., Li Q., Chen F. N., Dai Y., Luo F., Li L. Q., Corros. Sci., 2011, 53(4), 1401
[8] Taylor S. R., Chambers B. D., Corros., 2008, 64(3), 255
[9] Salasi M., Shahrabi T., Roayaei E., Aliofkhazraei M., Mater. Chem. Phys., 2007, 104(1), 183
[10] Aramaki K., Corros. Sci., 2002, 44(4), 871
[11] Li Y., Zhang Z. G., Shen D. G., Ma Q. L., Technol. Dev. Chem. Ind., 2008, 37(10), 17
[12] Zhang C., Zhao J. M., Acta Phys. Chim. Sin., 2014, 30(4), 677
[13] Zhao J. M., Duan H. B., Jiang R. J., Corros. Sci., 2015, 91, 108
[14] Zhang B. R., He C. J., Chen X., Tian Z. P., Li F. T., Corros. Sci., 2015, 90(1), 585
[15] Zhao L. N., Xu C. C., Corros. Prot., 2008, (8), 460
[16] Ren X. G., Zhou J. M., Song Y. J., Liu D., Pet. Geol. Recovery Effic., 2010, 17(6), 104
[17] Wang L., Hu R., Wang X. H., Li J. S., Wang Y. C., Chen H., China Pet. Mach., 2006, 34(10), 1
[18] Chen G. H., Study of the Inhibition Mechanism and Synergistic Effect of Corrosion Inhibitors in Sweet System, Beijing Univ. Chem. Tech-nol., Beijing, 2012
[19] Zeng J., Ind. Water Treat., 1984, 4(1),14
[20] Ni T. J., Wang W. X., Cai L. K., Corros. Prot., 2001, 22(11), 479
[21] Li H. H., Wu J. Q., Yi S. Z., Hangzhou Chem. Ind., 2007, 37(2), 17
[22] Zhu Y. L., Guo X. P., J. Chin. Soc. Corros. Prot., 2008, 28(5), 271

Synergistic Inhibition Effect of Sodium Silicate and Acrylamide on the Corrosion of Carbon Steel in a High-concentration KCl Solution

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Nabila AISSIOU, Moussa BOUNOUGHAZ, Amel DJEDDI. Lignin-Phenylhydrazone as a Corrosion Inhibitor of API X52 Carbon Steel in 3.5% NaCl and 0.1 mol/L HCl Medium [J]. Chemical Research in Chinese Universities, 2021, 37(3): 718-728.
[2]	LIU Junbo, ZHAO Wensi, TANG Shanshan, JIN Ruifa. Theoretical Design and Adsorption Properties of Molecularly Imprinted Polymers Obtained from Chloramphenicol and Acrylamide [J]. Chemical Research in Chinese Universities, 2020, 36(5): 915-920.
[3]	LU Yuan, ZHANG Chen, WANG Wei, ZHAO Jingmao. Study of the Synergistic Effect Between Corrosion Inhibitors by Using Fractional Free Volume [J]. Chemical Research in Chinese Universities, 2019, 35(6): 1046-1051.
[4]	YU Meng, LIU Miao. Adsorption of Dyes Using Multi-walled Carbon Nanotube Hydrogel [J]. Chemical Research in Chinese Universities, 2019, 35(2): 311-318.
[5]	HU Hao, JIANG Mingyan, XIE Lijun, HU Gang, ZHANG Cuirong, ZHANG Lixia, ZHOU Shunguang, ZHANG Meihui, GONG Ping. Design, Synthesis and Pharmacological Evaluation of Novel 4-Phenoxyquinoline Derivatives as Potential Antitumor Agents [J]. Chemical Research in Chinese Universities, 2015, 31(5): 746-755.
[6]	CHEN Jiaojiao, YIN Yue, FU Hongjun, LI Qifeng, ZOU Jiwei. Preparation and Chiral Recognition of Thermosensitive Poly(N-isopropylacrylamide) Microgels Containing Modified L-Phenylalanine Groups [J]. Chemical Research in Chinese Universities, 2015, 31(4): 664-668.
[7]	LU Gui-qian, ZUO Hua-jiang, DONG Wei-min, WU Ding-cai, FU Ruo-wen. Preparation and Antibacterial Activity of Copolymer of Methacryloxyethyldimethyl Dodecyl Ammonium Bromide/Acrylamide [J]. Chemical Research in Chinese Universities, 2012, 28(6): 1095-1100.
[8]	CHEN Guo-hao, ZHAO Jing-mao . Corrosion Inhibition of Imidazoline Derivates with Benzene Rings on Mild Steel in CO₂-Saturated Brine Solution [J]. Chemical Research in Chinese Universities, 2012, 28(4): 691-695.
[9]	XU Liang-zhong , XU Zhong-jie, ZHANG Gong-sheng, ZHOU Kai , ZHAI Zhi-wei . Synthesis, Characterization and Biological Activities of Novel Acrylamide Compounds [J]. Chemical Research in Chinese Universities, 2008, 24(5): 575-578.
[10]	GUO Yi, XU Jin-jie, LI Jun , YANG Wen-sheng. Formation of Na_1+xV₃O₈ Nanoribbon Thin Film from V₂O₅ Xerogel on Sodium Silicate Glass Substrate [J]. Chemical Research in Chinese Universities, 2007, 23(4): 381-383.
[11]	GUO Yi, XU Jin-jie, LI Jun , YANG Wen-sheng. Formation of Na1+xV3O8 Nanoribbon Thin Film from V2O5 Xerogel on Sodium Silicate Glass Substrate [J]. Chemical Research in Chinese Universities, 2007, 23(4): 381-383.
[12]	LI Liu-zhu, MAO Lu-yuan, WANG Xiu-li, YANG Yong, ZHUANG Yin-feng. Synthesis and Flocculation Property of Chitosan-Acrylamide Graft Copolymer [J]. Chemical Research in Chinese Universities, 2004, 20(2): 221-224.
[13]	ZHANG Guo-an, BAO Hui-min, FAN Hui-zhi, YANG Peng-yuan. Non-decoloured In-gel Digestion of Coomassie Blue-stained Proteins [J]. Chemical Research in Chinese Universities, 2003, 19(4): 399-403.
[14]	GAO Qing-yu, LIU Zhi-gui, GUAN Hui-li, YANG Geng-xu, YU Xian-da. Fluorescence and Photosensitizing Behavior of N-(p-Phenoxyphenyl)methacrylamide and Its Polymer [J]. Chemical Research in Chinese Universities, 2002, 18(1): 56-60.
[15]	DONG Jian-hua, DENG Chao, QIU Kun-yuan, FENG Xin-de. Initiation Mechanism of Polymerization of Acryl-amide by Ceric Ion/2-Benzoyl Acetanilide System [J]. Chemical Research in Chinese Universities, 1994, 10(4): 327-332.