Synthesis and Electrochemical Properties of a Novel Poly(ether sulfone) with Oligoaniline Pendants

doi:10.1007/s40242-015-5149-4

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (6): 1066-1071.doi: 10.1007/s40242-015-5149-4

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Synthesis and Electrochemical Properties of a Novel Poly(ether sulfone) with Oligoaniline Pendants

LI Fangfei¹, WANG Jiayu¹, ZHOU Mingjuan², LIU Xincai², WANG Ce², CHAO Danming²

1. State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2015-04-13 Revised:2015-07-15 Online:2015-11-01 Published:2015-09-02
Contact: CHAO Danming E-mail:chaodanming@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21104024), the Jilin Province Science and Technology Department Project, China(No.20130522139JH), the Functional Research Funds for the Central Universities, China(No. JCKY-QKJC07) and the Open Project of State Key Laboratory of Superhard Materials(Jilin University), China(No.201403).

Abstract

Abstract:

A novel poly(ether sulfone) with oligoaniline pendants(PESOP) was prepared by K₂CO₃-mediated nucleophilic polycondensation and characterized with Fourier-transform infrared spectrometry(FTIR), ¹H nuclear magnetic resonance(¹H NMR) and gel permeation chromatography(GPC). The cyclic voltammetry(CV) curve of PESOP reveals the reversible electroactivity. In the electrochromism study, PESOP film exhibited good electrochromic properties with a high contrast value, moderate switching time and acceptable coloration efficiency. After running 1000 cycles, the PESOP/indium-tin oxide(ITO) electrochromic device remained unchanged except for the drifting of base line, which certified its good electro-photo stability of the fabricated electrochromic device. Moreover, the polarization technique and electrochemical impedance spectroscopy(EIS) were used to study the anticorrosion performance of PESOP coatings on the cold rolled steel(CRS) in a 5%(mass fraction) NaCl solution. All the results indicate that the obtained PESOP is a competitive candidate as anticorrosion material.

Key words: Electroactive, Oligoaniline, Electrochromism, Anticorrosion

LI Fangfei, WANG Jiayu, ZHOU Mingjuan, LIU Xincai, WANG Ce, CHAO Danming. Synthesis and Electrochemical Properties of a Novel Poly(ether sulfone) with Oligoaniline Pendants[J]. Chemical Research in Chinese Universities, 2015, 31(6): 1066-1071.

References

[1] Pron A., Gawrys P., Zagorska M., Djurado D., Demadrille R., Chem. Soc. Rev., 2010, 39, 2577
[2] Bai H., Shi G., Sensors, 2007, 7, 267
[3] Li T., Zhang L., Chen Y., Guo Y., Du X., Chem. J. Chinese Universities, 2015, 36(4), 772
[4] Nasirian S., Moghaddam H. M., Polymer, 2014, 55, 1866
[5] Zhang X., Wu X., Yu L., Yang B., Zhou J., Synth. Met., 2015, 200, 74
[6] Sun J., Zhu Z., Lai J., Luo J., Liu X., Chem. J. Chinese Universities, 2015, 36(3), 581
[7] Wei Z., Faul C. F. J., Macromol. Rapid Commun., 2008, 29, 280
[8] Gao J., Liu D., Sansinena J., Wang H., Adv. Fnuct. Mater., 2004, 14, 537
[9] Huang H. Y., Lee Y. T., Yeh L. C., Jian J. W., Huang T. C., Liang H. T., Yeh J. M., Chou Y. C., Polym. Chem., 2013, 4, 343
[10] Chao D., He L., Berda E. B., Wang S., Jia X., Wang C., Polymer, 2013, 54, 3223
[11] Chao D., Lu X., Chen J., Zhao X., Wang L., Zhang W., Wei Y., J. Polym. Sci. Part A: Polym. Chem., 2006, 44, 477
[12] Lin S. C., Wu C. S., Yeh J. M., Liu Y. L., Polym. Chem., 2014, 5, 4235
[13] Chao D., Wang S., Yang R., Berda E. B., Wang C., Colloid and Polymer Science, 2013, 291, 2631
[14] Yeh L. C., Huang T. C., Huang Y. P., Huang H. Y., Chen H. H., Yang T. I., Yeh J. M., Electrochimica Acta, 2013, 94, 300
[15] Wang S., Chao D., Berda E. B., Jia X., Yang R., Wang X., Jiang T., Wang C., RSC Advances, 2013, 3, 4059
[16] Hickner M. A., Ghassemi H., Kim Y. S., Einsla B. R., McGrath J. E., Chem. Rev., 2004, 104, 4587
[17] Yu L., Zhang Y., Liu J., Chem. J. Chinese Universities, 2014, 35(5), 1100
[18] Chao D., Jia X., Liu H., He L., Cui L., Wang C., Berda E. B., J. Polym. Sci. Part A: Polym. Chem., 2011, 49, 1605
[19] Gamboa S. A., Gonzalez-Rodriguez J. G., Valenzuela E., Campillo B., Sebastian P. J., Reyes-Rojas A., Electrochimica Acta, 2006, 51, 4045
[20] Weng C. J., Huang J. Y., Huang K. Y., Jhuo Y. S., Tsai M. H., Yeh J. M., Electrochimica Acta, 2010, 55, 8430
[21] Bockris J. O. M., Reddy A. K., Modern Electrochemistry: an Introduction to an Interdisciplinary Area, Plenum Publishing Corporation, New York, 1973
[22] Chen L., Yu Y., Mao H., Lu X., Yao L., Zhang W., Wen Y., Synth. Met., 2005, 149, 129
[23] Chang K. C., Jang G. W., Peng C. W., Lin C. Y., Shieh J. C., Yeh J. M., Yang J. C., Li W. T., Electrochimica Acta, 2007, 52, 5191

Synthesis and Electrochemical Properties of a Novel Poly(ether sulfone) with Oligoaniline Pendants

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