Preparation and Pseudo-capacitance Performance of NiCo2O4 Nanosheets

doi:10.1007/s40242-019-9172-8

Abstract

Abstract: Ternary nickel cobaltite(NiCo₂O₄), as a promising electrode material for supercapacitors, has attracted increasing attention for its excellent electrochemical properties. In this study, novel NiCo₂O₄ nanosheets were rationally designed and prepared using dealloying process, followed by an oxidation treatment. The as-prepared sample was characterized by microstructural and electrochemical techniques in view of its possible application in supercapacitors. The as-prepared sample exhibited high specific capacitance and excellent durability. The specific capacitance reached 663 F/g at 1 A/g and the rate capacitance high up to 73.6% when the current density increased from 1 A/g to 20 A/g. After 5000 cycles of galvanostatic charge-discharge durability test at 4 A/g, the capacity retention rate was 82.1%. The results indicate that versatile dealloying can be used to prepare robust electrode for supercapacitor application.

Key words: Rapid-solidification, Dealloying, Nickel cobaltate, Nanosheet, Pseudo-capacitance

ZHOU Qi, JIAO Sunzhi, ZHENG Bin, LI Zhiyang. Preparation and Pseudo-capacitance Performance of NiCo₂O₄ Nanosheets[J]. Chemical Research in Chinese Universities, 2019, 35(6): 957-961.

References

[1] Simon P., Gogotsi Y., Nature Materials, 2008, 7(11), 845
[2] Zhang L. L., Zhao X. S., Chem. Soc. Rev., 2009, 38(9), 2520
[3] Snook G. A., Kao P., Best A. S., J. Power Sources, 2011, 196(1), 1
[4] Zhao J., Jiang Y., Fan H., Liu M., Zhuo O., Wang X., Wu Q., Yang L., Ma Y., Hu Z., Adv. Mater., 2017, 29(11), 1604569
[5] Zou Y., Cai C., Xiang C., Huang P., Chu H., She Z., Xu F., Sun L., Kraatz H. B., Electrochim. Acta, 2018, 261, 537
[6] Bi R. R., Wu X. L., Cao F. F., Jiang L. Y., Guo Y. G., Wan L. J., The Journal of Physical Chemistry C, 2010, 114(6), 2448
[7] Xia H., Meng Y. S., Yuan G., Cui C., Lu L., Electrochemical and Solid-state Letters, 2012, 15(4), A60
[8] Zhai S., Wang C., Karahan H. E., Wang Y., Chen X., Sui X., Huang Q., Liao X., Wang X., Chen Y. J. S., Small, 2018, 14(29), 1800582
[9] Arunachalam R., Prataap R. K. V., Raj R. P., Mohan S., Vijayakumar J., Peter L., Al Ahmad. M., Surface Engineering, 2019, 35(2), 103
[10] Liu M., Wang X., Zhu D., Li L., Duan H., Xu Z., Wang Z., Gan L., Chem. Eng. J., 2017, 308, 240
[11] Ouyang Y., Xia X., Ye H., Wang L., Jiao X., Lei W., Hao Q., ACS Applied Materials & Interfaces, 2018, 10(4), 3549
[12] Jiao Y., Hong W., Li P., Wang L., Chen G., Appl. Catal. B:Environ., 2019, 244, 732
[13] Pang H., Li X., Zhao Q., Xue H., Lai W. Y., Hu Z., Huang W., Nano Energy, 2017, 35, 138
[14] Qiu D., Ma X., Zhang J., Zhao B., Lin Z., Chem. Phys. Lett., 2018, 710, 188
[15] Shi Z., Xing L., Liu Y., Gao Y., Liu J., Carbon, 2018, 129, 819
[16] Raj S., Srivastava S. K., Kar P., Roy P., Electrochim. Acta, 2019, 302, 327
[17] Chen S., Zhu J., Wu X., Han Q., Wang X., ACS Nano, 2010, 4(5), 2822
[18] Chi H. Z., Wu Y. Q., Shen Y. K., Zhang C., Xiong Q., Qin H., Electrochim. Acta, 2018, 289, 158
[19] Xie Y., Yang C., Chen P., Yuan D., Guo K., J. Power Sources, 2019, 425, 1
[20] Zhang G., Lou X. W., Adv. Mater., 2013, 25(7), 976
[21] Wang T., Guo Y., Zhao B., Yu S., Yang H. P., Lu D., Fu X. Z., Sun R., Wong C. P., J. Power Sources, 2015, 286, 371
[22] Bhagwan J., Nagaraju G., Ramulu B., Sekhar S. C., Yu J. S., Electrochim. Acta, 2019, 299, 509
[23] Chen W. C., Hu C. C., Wang C. C., Min C. K., J. Power Sources, 2004, 125(2), 292
[24] Li Y., Han X., Y T. F., He Y. B., Li X. F., J. Energy Chem., 2019, 31, 54
[25] Fu H. Y., Wang Z. Y., Li Y. H., Zhang Y. F., Mater. Res. Innov., 2015, 19(Suppl. 4), S255
[26] Jokar E., Iraji Zad A., Shahrokhian S., J. Solid State Electr., 2015, 19(1), 269
[27] Zhang Y., Wang S. W., Gao H. L., Zhao S. Q., Chinese Journal of Power Sources, 2018, 42(2), 212
[28] Weissmüller J., Sieradzki K., Mrs. Bull., 2018, 43(1), 14
[29] Wang N., Sun B. L., Zhao P., Yao M., Hu W. C., Komarneni S., Chem. Eng. J., 2018, 345, 31
[30] Feng X., Huang Y., Li C., Chen X., Zhou S., Gao X., Chen C., Chem. Eng. J., 2019, 368, 51
[31] Zhou Q., Zheng B., Wang Y. F., Zheng S. Z., J. Materials Science Engineering of Powder Metallurgy, 2016, 21(5), 795
[32] Zhou Q., Zheng B., Li Z. Y., Wang Y. F., Feng J. W., Chinese Journal of Inorganic Chemistry, 2017, 33(8), 1416
[33] Pang M. J., Jiang S., Long G. H., Ji Y., Han W., Wang B., Liu X. L., Xi Y. L., Xu F. Z., Wei G. D., RSC Advances, 2016, 6(72), 67839
[34] Sun J., Wang W., Yu D., J. Electron. Mater., 2019, 48(6), 3833
[35] Li W., Yang F., Hu Z., Liu Y., J. Alloy. Compd., 2018, 749, 305
[36] Fu H. Y., Wang Z. Y., Li Y. H., Zhang Y. F., Mater. Res. Innov., 2015, 19, S255

Preparation and Pseudo-capacitance Performance of NiCo₂O₄ Nanosheets

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