Studies on Isosorbide-enhanced Biodegradable Poly(ethylene succinate)

doi:10.1007/s40242-019-8227-1

Chemical Research in Chinese Universities ›› 2019, Vol. 35 ›› Issue (2): 345-352.doi: 10.1007/s40242-019-8227-1

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Studies on Isosorbide-enhanced Biodegradable Poly(ethylene succinate)

QU Dezhi¹, ZHANG Fuchen¹, GAO Hongwei¹, WANG Qiuxia¹, BAI Yongping^1,2, LIU Huihui³

1. School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, P. R. China;
2. Wuxi HIT Limited Corporation & Research Institute of New Materials, Wuxi 214183, P. R. China;
3. Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621000, P. R. China

Received:2018-07-17 Revised:2018-11-14 Online:2019-04-01 Published:2019-04-30
Contact: BAI Yongping, LIU Huihui E-mail:baifengbai@hit.edu.cn;liuhuihui9088@caep.cn
Supported by:
Supported by the Fund of Wuxi HIT Limited Corporation & Research Institute of New Materials, China(No.BM2017006).

Abstract

Abstract: To improve the mechanical properties of bio-based poly(ethylene succinate), the sugar monomer isosorbide, which is relatively easy to obtain, was used as a copolymerized third monomer to synthesize poly(ethylene-co-isosorbide succinate), a 100% biomass copolyester. The effects of isosorbide on the crystallinity and thermal properties of copolyester were studied by nuclear magnetic resonance(¹H NMR), differential scanning calorimeter (DSC), and thermogravimetric(TG). Owing to its distinct rigid bicyclic structure, isosorbide can improve the glass transition temperature of the copolyester and decrease the crystallization rate, as well as accelerate the hydrolysis of the copolyester. Simultaneously, the introduction of isosorbide can effectively improve the antistatic properties of copolyester.

Key words: Bio-based polyester, Isosorbide, Poly(ethylene-co-isosorbide succinate), Antistatic

QU Dezhi, ZHANG Fuchen, GAO Hongwei, WANG Qiuxia, BAI Yongping, LIU Huihui. Studies on Isosorbide-enhanced Biodegradable Poly(ethylene succinate)[J]. Chemical Research in Chinese Universities, 2019, 35(2): 345-352.

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Studies on Isosorbide-enhanced Biodegradable Poly(ethylene succinate)

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