Acetic Acid Assistant Hydrogenation of Graphene Sheets with Ferromagnetism

doi:10.1007/s40242-018-8001-9

Abstract

Abstract: Ferromagnetism of pure carbon-based materials has been widely researched for several years. In therocially and experimentally, semi-hydrogenation graphene sheets exhibit ferromagnitism, which is related to the degree of hydrogenation. Here we reported the controllable hydrogenation of graphene using ball-milling method with acetic acid as hydrogenating agent. The hydrogenation graphene sheets were characterized by means of transmission electron microscopy(TEM), Raman spectroscopy and X-ray photoelectron spectroscopy, and magnetic measurement. The relusts of Raman spectroscopy demonstrate that the relative intensity of D band increases with the hydrogenation degree. The resluts of magnetic meansurement indicate the maximal magnetic moment of 0.274 A·m²/kg at 2 K for semi-hydrogenation graphene.

Key words: Graphene, Hydrogenated graphene, Ball-milling, Ferromagnetism

SUN Qiushi, WANG Xiaofeng, LI Benxian, WU Yunpeng, ZHANG Ziqing, ZHANG Xinyang, ZHAO Xudong, LIU Xiaoyang. Acetic Acid Assistant Hydrogenation of Graphene Sheets with Ferromagnetism[J]. Chemical Research in Chinese Universities, 2018, 34(3): 344-349.

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