Kinetic and Thermodynamic Studies on Adsorption of Cu2+, Pb2+, Methylene Blue and Malachite Green from Aqueous Solution Using AMPS-modified Hazelnut Shell Powder

doi:10.1007/s40242-017-6243-6

Chemical Research in Chinese Universities ›› 2017, Vol. 33 ›› Issue (1): 112-118.doi: 10.1007/s40242-017-6243-6

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Kinetic and Thermodynamic Studies on Adsorption of Cu²⁺, Pb²⁺, Methylene Blue and Malachite Green from Aqueous Solution Using AMPS-modified Hazelnut Shell Powder

LÜ Linlin^1,2, JIANG Xiaojun¹, JIA Lian², AI Tian¹, WU Hang¹

1. School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, P. R. China;
2. School of Chemistry and Life Science, Anshan Normal University, Anshan 114005, P. R. China

Received:2016-06-13 Revised:2016-09-09 Online:2017-02-01 Published:2016-10-31
Contact: JIANG Xiaojun,E-mail:asjiangxiaojun@163.com E-mail:asjiangxiaojun@163.com
Supported by:
Supported by the Doctoral Research Fund of Liaoning Province, China(No.20141124) and the Program for High-end Talent Training in Anshan Science and Technology Bureau, China(No.20153473).

Abstract

Abstract:

A high-efficiency, low-cost and environment-friendly 2-acrylamide-2-methyl propane sulfonic acid (AMPS)-modified hazelnut-shell-based adsorbent(AHS) was synthesized and used to adsorb Cu²⁺, Pb²⁺, methylene blue(MB) and malachite green(MG) from aqueous solutions. The AHS was characterized by means of SEM, BET, FTIR and XPS. Different experimental parameters were evaluated in batch adsorption experiments to determine the optimal adsorption conditions. Adsorption kinetics shows that the adsorption rate is well represented by the pseudo-second-order rate model, and the Langmuir model gives the best fit adsorption isotherm. The Langmuir maximum adsorption capacities were found to be 21.14 mg/g for Cu²⁺, 32.74 mg/g for Pb²⁺, 68.03 mg/g for MB and 263.16 mg/g for MG, respectively, while the adsorption capacities could be maintained above 90% even after ten adsorption-desorption cycles. The experimental results show that AHS could be applied to treat both industrial and municipal wastewaters.

Key words: Hazelnut shell, Kinetic, Thermodynamic, Adsorption, Metal ion, Dye

LÜ Linlin, JIANG Xiaojun, JIA Lian, AI Tian, WU Hang. Kinetic and Thermodynamic Studies on Adsorption of Cu²⁺, Pb²⁺, Methylene Blue and Malachite Green from Aqueous Solution Using AMPS-modified Hazelnut Shell Powder[J]. Chemical Research in Chinese Universities, 2017, 33(1): 112-118.

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Kinetic and Thermodynamic Studies on Adsorption of Cu²⁺, Pb²⁺, Methylene Blue and Malachite Green from Aqueous Solution Using AMPS-modified Hazelnut Shell Powder

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