Quantitative Determination of Cr in Ink by Laser-induced Breakdown Spectroscopy(LIBS) Using ZnO as Adsorbent

doi:10.1007/s40242-015-5210-3

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (6): 909-913.doi: 10.1007/s40242-015-5210-3

• Articles • Previous Articles Next Articles

Quantitative Determination of Cr in Ink by Laser-induced Breakdown Spectroscopy(LIBS) Using ZnO as Adsorbent

WEI Jiao^1,2, ZHANG Tianlong^1,2, DONG Juan^1,2, SHENG Liwen^1,2, TANG Hongsheng^1,2, YANG Xiaofeng², LI Hua^1,2,3

1. Institute of Analytical, Northwest University, Xi'an 710069, P. R. China;
2. College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China;
3. College of Chemistry and Chemical Engineering, Xi'an Shiyou University, Xi'an 710065, P. R. China

Received:2015-05-28 Revised:2015-09-02 Online:2015-11-01 Published:2015-09-08
Contact: LI Hua E-mail:huali@nwu.edu.cn
Supported by:
Supported by the National Special Fund for the Development of Major Scientific Instruments and Equipment of China (No.2011YQ030113), the National Natural Science Foundation of China(Nos.21175106, 21375105) and the Research Fund for the Doctoral Program of Higher Education of China(No.20126101110019).

Abstract

Abstract:

Laser-induced breakdown spectroscopy(LIBS) technique was applied to detecting chromium in ink with ZnO as adsorbent, and the LIBS spectra were preprocessed by wavelet denoising. The laser energy and delay time were optimized depending on the signal-to-noise ratio(SNR) and intensity of three analysis atomic lines(Cr 425.43 nm, Cr 427.48 nm and Cr 428.97 nm). Compared with other analysis lines, atomic line of Cr 427.48 nm was selected as the analysis line for the quantitative analysis of Cr in ink as the calibration curve of it showed a better linear relationship (correlation coefficient R²=0.9778), and the relative error of Cr in the measured ink was 52.96%. Since the single spectral line used for calibration curve method is often influenced by matrix effect and other factors, partial least squares regression(PLS) as multivariate calibration method has been applied to predicting the concentration of Cr in ink, and the relative error of Cr in the measured ink was 10.48%. The result obtained from the PLS method was better than that from the calibration curve when comparing the relative error, demonstrating that, based on adsorbent, LIBS combined with PLS provides an effective, practical and convenient technique for the determination of trace element in aqueous solution.

Key words: Laser-induced breakdown spectroscopy, Zinc oxide, Partial least square, Chromium, Ink

WEI Jiao, ZHANG Tianlong, DONG Juan, SHENG Liwen, TANG Hongsheng, YANG Xiaofeng, LI Hua. Quantitative Determination of Cr in Ink by Laser-induced Breakdown Spectroscopy(LIBS) Using ZnO as Adsorbent[J]. Chemical Research in Chinese Universities, 2015, 31(6): 909-913.

References

[1] Oujja M., Vila A., Rebollar E., Garc?a J. F., Castillejo M., Spectrochim. Acta, Part B, 2005, 60, 1140
[2] Trejos T., Flores A., Almirall J. R., Spectrochim. Acta, Part B, 2010, 65, 884
[3] El Sherbini A. M., El Sherbini T. M., Hegazy H., Cristoforetti G., Legnaioli S., Palleschi V., Pardini L., Salvetti A., Tognoni E., Spectrochim. Acta, Part B, 2005, 60, 1573
[4] George A. E., Zachariadis S., Eur. J. Chem., 2011, 9, 213
[5] Singh P., Negi J. S., Rawat M. S. M., Pant G. J. N., Nat. Prod. Res., 2012, 26, 161
[6] Ulusoy H. ?., Gürkan R., Aksoy Ü., Akçay M., Microchem. J., 2011, 99, 76
[7] Zhang H. X., Rui Y. K., Eur. J. Chem., 2010, 8, 782
[8] Bentlina F. R. S., Pozebona D., Mellob P. A., Flores E. M. M., Anal. Chim. Acta, 2007, 602, 23
[9] Srogi K., Anal. Lett., 2008, 41, 677
[10] Hanafi M., Omar M. M., Gamal Y. E. E. D., Radiat. Phys. Chem., 2000, 57, 11
[11] Kuzuya M., Aranami H., Spectrochim. Acta, Part B, 2000, 55, 1423
[12] Tognoni E., Palleschi V., Corsi M., Cristoforetti G., Spectrochim. Acta, Part B, 2002, 57, 1115
[13] Kuzuya M., Murakami M., Maruyama N., Spectrochim. Acta, Part B, 2003, 58, 957
[14] Yun J., Klenze R., Kim J., Appl. Spectrosc., 2002, 56, 437
[15] Boyain-Goitia A. R., Beddow D. C. S., Griffiths B. C., Helmut T., Appl. Opt., 2003, 42, 6119
[16] Morel S., Leone N., Adam P., Amouroux J., Appl. Opt., 2003, 42, 6184
[17] Corsi M., Cristoforetti G., Hidalgo M., Legnaioli S., Palleschi V., Salvetti A., Tognoni E., Allebona C., Appl. Opt., 2003, 42, 6133
[18] Sheng L. W., Zhang T. L., Wang K., Tang H. S., Li H., Chem. Res. Chinese Universities, 2015, 31(1), 107
[19] Michel A. P. M., Spectrochim. Acta, Part B, 2010, 65, 185
[20] Pearman W., Scaffidi J., Angel S. M., Appl. Opt., 2003, 42, 6085
[21] Cáceres J. O., Tornero L. J., Telle H. H., Ureña A. G., Spectrochim. Acta, Part B, 2001, 56, 831
[22] Charfi B., Harith M. A., Spectrochim. Acta, Part B, 2002, 57, 1141
[23] Yaroshchyk P., Morrison R. J. S., Body D., Chadwick B. L., Spectrochim. Acta, Part B, 2005, 60, 986
[24] Fichet P., Mauchien P., Wagnerand C., Moulin J. F., Anal. Chim. Acta, 2001, 429, 269
[25] Díaz Pace D. M., D'Angelo C. A., Bertuccelli D., Bertuccelli G., Spectrochim. Acta, Part B, 2006, 61, 929
[26] Chen Z. J., Li H. K., Liu M., Li R. H., Spectrochim. Acta, Part B, 2008, 63, 64
[27] Babushok V. I., DeLucia F. C., Gottfried J. L., Miziolek A. W., Spectrochim. Acta, Part B, 2006, 61, 999
[28] Zhu D. H., Chen J. P., Lu J., Ni X. W., Anal. Methods, 2012, 4, 819
[29] Alamelu D., Sarkar A., Aggarwal S. K., Talanta, 2008, 77, 256
[30] Chen Z. J., Godwal Y., Tsui Y. Y., Fedosejevs R., Appl. Opt., 2010, 49, 87
[31] Chen Z., Li H., Zhao F., Li R., Spectrochim. Acta, Part B, 2008, 63, 64
[32] Haider A. F. M. Y., Ullah M. H., Khan Z. H., Kabir F., Abedin K. M., Opt. Laser Technol., 2014, 56, 299
[33] Wang X. Y., Fu Z. K., Eng. Appl. Artif. Intel., 2010, 23, 862
[34] Sarkar A., Karki V., Aggarwal S. K., Maurya G. S., Kumar R., Spectrochim. Acta, Part B, 2015, 108, 8
[35] Yao S. C., Lu J. D., Dong M. R., Chen K, Li J. Y., Li J., Appl. Spectrosc., 2011, 65, 1197

Quantitative Determination of Cr in Ink by Laser-induced Breakdown Spectroscopy(LIBS) Using ZnO as Adsorbent

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	YANG Shengqing, ZHAO Jinnan, CHEN Shuo, ZHAO Jingbo. Flexible Self-healing Cross-linked Polyamides Synthesized Through Bulk Michael Addition, Polycondensation, and Diels-Alder Reaction [J]. Chemical Research in Chinese Universities, 2022, 38(4): 968-973.
[2]	XU Yanyan, LI Maogang, FENG Ting, JIAO Long, WU Fengtian, ZHANG Tianlong, TANG Hongsheng, LI Hua. Quantitative Analysis of Methanol in Methanol Gasoline by Calibration Transfer Strategy Based on Kernel Domain Adaptive Partial Least Squares(kda-PLS) [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1057-1064.
[3]	ZHAO Lili, GONG Zhou, ZHAO Qun, ZHANG Lihua, and ZHANG Yukui. Deciphering In-vivo Cross-linking Mass Spectrometry Data for Dynamic Protein Structure Analysis [J]. Chemical Research in Chinese Universities, 2022, 38(3): 758-762.
[4]	SONG Lili, LI Hui, LI Ting, XU Jiaquan and CHEN Huanwen. Sequential Speciation Analysis of Heavy Metals in Drinking Water Pipe Scales by Mass Spectrometry [J]. Chemical Research in Chinese Universities, 2022, 38(3): 774-781.
[5]	BI Shuai, MENG Fancheng, ZHANG Zixing, WU Dongqing, ZHANG Fan. Covalent Organic Frameworks with trans-Dimensionally Vinylene-linked π-Conjugated Motifs [J]. Chemical Research in Chinese Universities, 2022, 38(2): 382-395.
[6]	CUI Yumeng, MIAO Zhuang, LIU Qi, JIN Fenchun, ZHAI Yufeng, ZHANG Lingyan, WANG Wenli, WANG Ke, LIU Guiyan, ZENG Yongfei. Construction of a Three-dimensional Covalent Organic Framework via the Linker Exchange Strategy [J]. Chemical Research in Chinese Universities, 2022, 38(2): 402-408.
[7]	WANG Dong, LI Zhenwei, ZHANG Qian, LIU Jie, YANG Yu, HAN Jishu, WANG Lei. Small Things Make a Big Difference: the Small-molecule Cross-linker of Robust Water-soluble Network Binders for Stable Si Anodes [J]. Chemical Research in Chinese Universities, 2021, 37(2): 304-310.
[8]	SHI Chengying, YANG Jiayu, LIU Yang, WANG Yanmiao, XU Wenge, XU Yiquan, HU Wei, LIU Baijun. Thermally Conductive Study of Polyethylene/Al₂O₃ Composite Networks Cross-linked by Electron Beam Irradiation [J]. Chemical Research in Chinese Universities, 2020, 36(5): 940-945.
[9]	FU Pengyan, MO Junting, SUN Sisi, YIN Shaoyun, WANG Haiping, PAN Mei. Acid-base Vapor Sensing Enabled by ESIPT-attributed Cd(II) Coordination Polymer with Switchable Luminescence [J]. Chemical Research in Chinese Universities, 2020, 36(5): 755-759.
[10]	LIU Zhenchao, WANG Peng, HU Wei, LIU Baijun. Preparation and Properties of Hybrid Silane-crosslinked Sulfonated Poly(aryl ether ketone)s as Proton Exchange Membranes [J]. Chemical Research in Chinese Universities, 2019, 35(5): 937-944.
[11]	ZOU Xiaohu, WEI Zhizhi, DU Jing, WANG Xiaotao, ZHANG Gaowen. Preparation and Properties of Magnetic-fluorescent Microporous Polymer Microspheres [J]. Chemical Research in Chinese Universities, 2018, 34(4): 684-690.
[12]	CUI Jian, WANG Ende, HOU Zhimin, ZHOU Rui, JIAO Xinqian. Removal of Chromium(VI) from Groundwater Using Oil Shale Ash Supported Nanoscaled Zero-valent Iron [J]. Chemical Research in Chinese Universities, 2018, 34(4): 546-551.
[13]	SU Ping, CHEN Xiaonan, HE Zhangjing, YANG Yi. Preparation of Polyclonal Antibody and Development of a Biotin-streptavidin-based ELISA Method for Detecting Kanamycin in Milk and Honey [J]. Chemical Research in Chinese Universities, 2017, 33(6): 876-881.
[14]	SHI Xue, ZHOU Guowei. Preparation of Zinc-nickel-cobalt Ternary Oxide Nanosheets as Electrodes in Supercapacitors [J]. Chemical Research in Chinese Universities, 2017, 33(6): 939-945.
[15]	SU Jing, YU Mingyue, LIN Zhen, ZHAO Hang, LIU Haiyan. Effects of ZnO Nanoparticles on Rat Glioma C6 Cells [J]. Chemical Research in Chinese Universities, 2017, 33(6): 908-911.