A Green and Efficient Trinitration System for Aromatic Compounds with Bi(NO3)3·5H2O/[HMIM]ClO4 as Catalyst in HNO3/Ac2O

doi:10.1007/s40242-015-5087-1

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (5): 761-765.doi: 10.1007/s40242-015-5087-1

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A Green and Efficient Trinitration System for Aromatic Compounds with Bi(NO₃)₃·5H₂O/[HMIM]ClO₄ as Catalyst in HNO₃/Ac₂O

SUN Weizhi¹, YU Shitao², XIAN Mo¹

1. CAS Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, P. R. China;
2. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

Received:2015-03-11 Revised:2015-05-12 Online:2015-10-01 Published:2015-06-29
Contact: XIAN Mo, E-mail: xianmo@qibebt.ac.cn E-mail:xianmo@qibebt.ac.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21376255).

Abstract

Abstract:

To investigate the green trinitration method of aromatic compounds, with Lewis acid/ionic liquid as catalyst and HNO₃/Ac₂O as nitration reagent, a Lewis acid/ionic liquid/HNO₃/Ac₂O system was established. In various combinations of Lewis acids and ionic liquids, Bi(NO₃)₃·5H₂O/[HMIM]ClO₄ proved to be a very efficient catalyst for the trinitration of activated aromatic compounds and reusable for 3 times. Reaction conditions for the trinitration were optimized and yields of the trinitro products were from mild to excellent. This sulfuric acid-free system has the advantages of strong trinitration ability, low environment pollution, low toxicity, low cost and high potential for industrial application.

Key words: Green trinitration, Aromatic compound, Lewis acid, Ionic liquid, Acetyl nitrate

SUN Weizhi, YU Shitao, XIAN Mo. A Green and Efficient Trinitration System for Aromatic Compounds with Bi(NO₃)₃·5H₂O/[HMIM]ClO₄ as Catalyst in HNO₃/Ac₂O[J]. Chemical Research in Chinese Universities, 2015, 31(5): 761-765.

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A Green and Efficient Trinitration System for Aromatic Compounds with Bi(NO₃)₃·5H₂O/[HMIM]ClO₄ as Catalyst in HNO₃/Ac₂O

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