Catalysts for Hydration of Cyclohexene to Cyclohexanol

doi:10.1007/s40242-013-3091-x

Chemical Research in Chinese Universities ›› 2013, Vol. 29 ›› Issue (4): 743-746.doi: 10.1007/s40242-013-3091-x

• Articles • Previous Articles Next Articles

Catalysts for Hydration of Cyclohexene to Cyclohexanol

FANG De-ren^1,2, LU Jin-yan¹, ZHANG Hui-min², LI Jie², WANG Yan-yan²

1. Shandong Provincial Key Lab of Chemical Engineering, Yantai 264005, P. R. China;
2. Institute of Applied Catalysis, Yantai University, Yantai 264005, P. R. China

Received:2013-03-06 Revised:2013-06-05 Online:2013-08-01 Published:2013-07-15
Contact: FANG De-ren E-mail:fdr@ytu.edu.cn
Supported by:
Supported by the Science and Technology Development Project of Shandong Province, China(No.2012G0020224).

Abstract

Abstract:

The hydration of cyclohexene was determined in a stirred tank of 100 mL in a batch mode in the presence of modified or unmodified resin as catalyst. The ion-exchange sulfonate resin was modified with alkyl secondary amine. At an optimum amination rate of 15%, the conversion of cyclohexene reached to 22% and the selectivity of cyclohexanol was 95.6%. In a temperature range of 90―150 ℃, the activity and selectivity of the modified resin ca-talyst were much higher than those of the unmodified resin catalyst, which was attributed to the inclusion formed between cyclohexene and alkyl chain and also the quasi-lipophilic phase formed around the outer surface of resin beads. The formed quasi-lipophilic phase formed enhanced the conversion of cyclohexene and depressed the formation of by-products.

Key words: Hydration, Cyclohexene, Ion-exchange resin, Modification, Aminate rate

FANG De-ren, LU Jin-yan, ZHANG Hui-min, LI Jie, WANG Yan-yan. Catalysts for Hydration of Cyclohexene to Cyclohexanol[J]. Chemical Research in Chinese Universities, 2013, 29(4): 743-746.

[1]	TU Tingting, HUAN Shuangyan, KE Guoliang, ZHANG Xiaobing. Functional Xeno Nucleic Acids for Biomedical Application [J]. Chemical Research in Chinese Universities, 2022, 38(4): 912-918.
[2]	HOU Wenhui, OU Yu and LIU Kai. Progress on High Voltage PEO-based Polymer Solid Electrolytes in Lithium Batteries [J]. Chemical Research in Chinese Universities, 2022, 38(3): 735-743.
[3]	QIN Xudong, TANG Xiaohui, MA Yu, XU Hong, XU Qing, YANG Weiting, GU Cheng. Decorating Covalent Organic Frameworks with High-density Chelate Groups for Uranium Extraction [J]. Chemical Research in Chinese Universities, 2022, 38(2): 433-439.
[4]	XIAO Jiapeng, ZHANG Wenhui, ZHANG Shujing, LI Yu. Molecular Modification of Benzophenone Derivatives for Lower Bioenrichment and Toxicity Through the Pharmacophore Model [J]. Chemical Research in Chinese Universities, 2022, 38(2): 535-545.
[5]	FAN Huimin, WANG Bingwu, WANG Zheming, GAO Song. A Unique Layered Cu-formate Hydrate of Cu(HCOO) ₂·1/3H₂O: Structures, Dehydration, and Thermal and Magnetic Properties [J]. Chemical Research in Chinese Universities, 2022, 38(1): 107-116.
[6]	ZHOU Xue, WANG Chao, CHU Yueying, WANG Qiang, XU Jun, DENG Feng. Mechanistic Insight into Ethanol Dehydration over SAPO-34 Zeolite by Solid-state NMR Spectroscopy [J]. Chemical Research in Chinese Universities, 2022, 38(1): 155-160.
[7]	ZHANG Yunzhe, DAI Weili, WU Guangjun, GUAN Naijia, LI Landong. Catalytic Hydration of Aromatic Alkynes to Ketones over H-MFI Zeolites [J]. Chemical Research in Chinese Universities, 2022, 38(1): 173-180.
[8]	LI Xiaodan, GUO Mengyu, CHEN Chunying. Graphdiyne: from Preparation to Biomedical Applications [J]. Chemical Research in Chinese Universities, 2021, 37(6): 1176-1194.
[9]	ZHANG Mengqian, HE Peiyang, LI Yanmei. Contemporary Approaches to α,β-Dehydroamino Acid Chemical Modifications [J]. Chemical Research in Chinese Universities, 2021, 37(5): 1044-1054.
[10]	ZHANG Shujing, XIAO Jiapeng, CHEN Xinyi, LI Yu. Insulation and Flame Retardancy Improvement of PBDEs Using 3D-QSAR Model Combined with a Fuzzy Membership Function Method [J]. Chemical Research in Chinese Universities, 2021, 37(3): 729-738.
[11]	CHEN Zhijun, HAO Ming, QIAN Xiaoming, CHEN Wenyang, ZENG Ming, HUANG Juan, LI Ruixin, FAN Jintu, LIU Yanbo. Characterization on Modification and Biocompatibility of PCL Scaffold Prepared with Near-field Direct-writing Melt Electrospinning [J]. Chemical Research in Chinese Universities, 2021, 37(3): 578-583.
[12]	WU Ying, YAO Yu, WANG Lifeng, YU Yan. Recent Progress on Modification Strategies of Alloy-based Anode Materials for Alkali-ion Batteries [J]. Chemical Research in Chinese Universities, 2021, 37(2): 200-209.
[13]	LI Xianglin, ZHANG Qingyang, LI Bin, LI Zhijun, ZHANG Ziqing, JING Liqiang. Improved Photocatalytic Activity of Porous In₂O₃ by co-Modifying Nanosized CuO and Ag with Synergistic Effects [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1116-1121.
[14]	LIU Shuo, YANG Mingjie, GUO Weiwei. Programmable and Reversible Regulation of Catalytic Hemin@MOFs Activities with DNA Structures [J]. Chemical Research in Chinese Universities, 2020, 36(2): 301-306.
[15]	ZHAO Jie. Inspired by Grape Seed and Wine: Tannic Acid as a Modified Coating for Fabricating Highly Flexible, Transparent and Conductive Film [J]. Chemical Research in Chinese Universities, 2019, 35(5): 945-950.

Catalysts for Hydration of Cyclohexene to Cyclohexanol

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments