Adsorption of Zinc and Cyanide from Cyanide Effluents on Anionic Ion-exchange Resin

doi:10.1007/s40242-013-2070-6

Abstract

Abstract:

The adsorption of zinc and cyanide from cyanide effluents onto strong and weak basic anion exchange resins was studied in a batch adsorption system. Factors influencing the adsorption rates such as resin selection, resin amounts, contact time and temperature were studied and scanning electron microscopy-energy disperse spectroscopy(SEM-EDS) was used in the analysis. The present study shows that the adsorption capacity of resin 201×7 is better than that of resin 301. The adsorption process was relatively fast and came to equilibrium after 60 min. The kinetic data were analyzed with three models and the pseudo-second-order kinetic model was found to agree with the experimental data well. The equilibrium data could also be described well by Langmuir isotherm model. Thermodynamic parameters such as enthalpy change(ΔH⁰), free energy change(ΔG⁰) and entropy change(ΔS⁰) were calculated and the adsorption process was spontaneous and endothermic.

Key words: Ion-exchange, Adsorption, Adsorption isotherm, Adsorption kinetics, Thermodynamic parameter

ZHANG Ya-li, FANG Tao, YU Xian-jin. Adsorption of Zinc and Cyanide from Cyanide Effluents on Anionic Ion-exchange Resin[J]. Chemical Research in Chinese Universities, 2013, 29(1): 144-149.

[1]	SONG Jialong, WANG Zitao, LIU Yaozu, TUO Chao, WANG Yujie, FANG Qianrong, and QIU Shilun. A Three-dimensional Covalent Organic Framework for CO₂ Uptake and Dyes Adsorption [J]. Chemical Research in Chinese Universities, 2022, 38(3): 834-837.
[2]	WANG Guangbo, XIE Kehui, ZHU Fucheng, KAN Jinglan, LI Sha, GENG Yan, DONG Yubin. Construction of Tetrathiafulvalene-based Covalent Organic Frameworks for Superior Iodine Capture [J]. Chemical Research in Chinese Universities, 2022, 38(2): 409-414.
[3]	DI Zhengyi, MAO Yining, YUAN Heng, ZHOU Yan, JIN Jun, LI Cheng-Peng. Covalent Organic Frameworks(COFs) for Sequestration of⁹⁹TcO₄^– [J]. Chemical Research in Chinese Universities, 2022, 38(2): 290-295.
[4]	QIN Xudong, TANG Xiaohui, MA Yu, XU Hong, XU Qing, YANG Weiting, GU Cheng. Decorating Covalent Organic Frameworks with High-density Chelate Groups for Uranium Extraction [J]. Chemical Research in Chinese Universities, 2022, 38(2): 433-439.
[5]	ZHANG Jianhui, LIU Jianchuan, LIU Yaozu, WANG Yujie, FANG Qianrong, QIU Shilun. A Two-dimensional Covalent Organic Framework for Iodine Adsorption [J]. Chemical Research in Chinese Universities, 2022, 38(2): 456-460.
[6]	WANG Yuwen, CHENG Tiexin, ZHOU Guangdong. Study on the Mechanism of Asphaltenes Reducing Oil-Water Interfacial Tension [J]. Chemical Research in Chinese Universities, 2022, 38(2): 616-621.
[7]	LIU Ru-Shuai, XU Shuang, HAO Guang-Ping, LU An-Hui. Recent Advances of Porous Solids for Ultradilute CO₂ Capture [J]. Chemical Research in Chinese Universities, 2022, 38(1): 18-30.
[8]	SHI Chao, WANG Jiaze, LI Lin, LI Yi. High-throughput Screening of Aluminophosphate Zeolites for Adsorption Heat Pump Applications [J]. Chemical Research in Chinese Universities, 2022, 38(1): 161-166.
[9]	MA Yuying, HE Dayong, LIU Jiadi, WANG Yuannan, YANG Mei, WANG Hao, QIU Ju, LI Wenyan, LI Yongxin, WANG Ce. Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W₁₈O₄₉ Nanofibers [J]. Chemical Research in Chinese Universities, 2021, 37(3): 428-435.
[10]	LI Wenyan, LI Yanzi, LIU Jiadi, CHAO Shen, YANG Tianyi, LI Lijuan, WANG Ce, LI Xiang. A Novel Hollow Carbon@MnO₂ Electrospun Nanofiber Adsorbent for Efficient Removal of Pb²⁺ in Wastewater [J]. Chemical Research in Chinese Universities, 2021, 37(3): 496-504.
[11]	LUO Kexin, SU Qing, JU Pengyao, LI Xiaodong, LIU Ziqian, SUN Xiaoman, LI Guanghua, WU Qiaolin. Polyfunctional Conjugated Microporous Polymers for Applications in Direct C-H Arylation of Unactivated Arenes and Aqueous Adsorption of Aromatic Amines [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1302-1309.
[12]	WANG Yuannan, LI Wenyan, CHAO Shen, LI Yanzi, LI Xiang, HE Dayong, WANG Ce. Preparation of MnO₂ Loaded Hydrothermal Carbon-coated Electrospun PAN Fiber Membranes for Highly Efficient Adsorption and Separation of Cationic Dye [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1292-1301.
[13]	MANSOURI Said, MAJDOUBI Hicham, HADDAJI Younesse, TAMRAOUI Youssef, EL ACHABY Mounir, MANOUN Bouchaib, ABOURRICHE Abdelkrim, HANNACHE Hassan, OUMAM Mina. Optimization Studies of Porous Carbon Preparation from Oil Shale Using Response Surface Methodology and Its Application for Phenol Adsorption [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1339-1347.
[14]	LI Ying, PAN Bo, MIAO Hongyan, XU Humin, LIU Xuefeng, SHI Gang. Single and Binary Dye Adsorption of Methylene Blue and Methyl Orange in Alcohol Aqueous Solution via Rice Husk Based Activated Carbon: Kinetics and Equilibrium Studies [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1272-1278.
[15]	LIU Junbo, ZHAO Wensi, TANG Shanshan, JIN Ruifa. Theoretical Design and Adsorption Properties of Molecularly Imprinted Polymers Obtained from Chloramphenicol and Acrylamide [J]. Chemical Research in Chinese Universities, 2020, 36(5): 915-920.

Adsorption of Zinc and Cyanide from Cyanide Effluents on Anionic Ion-exchange Resin

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments