Kinetics of Atom Transfer Radical Polymerization of Methyl Methacrylate Initiated by Cellulose Chloroacetate in BMIMCl

doi:10.1007/s40242-013-2058-2

Abstract

Abstract:

The kinetics of atom transfer radical polymerization(ATRP) of methyl methacrylate(MMA) initiated by cellulose based macroinitator, cellulose chloroacetate, performed in ionic liquid(1-N-butyl-3-methylimidazolium chloride, BMIMCl), dimethyl sulfoxide(DMSO) and dimethyl formamide(DMF) were respectively studied in detail. The polymerizations were carried out under homogeneous conditions with CuBr as catalyst and 2,2′-bipyridine(bpy) as ligand. The dependences of the rate of polymerization on solvent, temperature, monomer/initiator ratio and catalyst/ligand ratio were presented. Plots of ln([M]₀/[M]_t) vs. time and molecular weight vs. conversion showed a linear dependence, indicating a constant number of propagating species throughout the polymerization as well as a negligible contribution of termination or transfer reactions. On the basis of an Arrhenius plot, the apparent energy of activation(ΔE_a^app) for ATRP of MMA in BMIMCl was 16.6 kJ/mol which is much lower than that in diphenyl ether.

Key words: Atom transfer radical polymerization(ATRP), Methyl methacrylate, Kinetics

LIN Chun-xiang, ZHAN Huai-yu, LIU Ming-hua, FU Shi-yu, LUCIA Lucian, . Kinetics of Atom Transfer Radical Polymerization of Methyl Methacrylate Initiated by Cellulose Chloroacetate in BMIMCl[J]. Chemical Research in Chinese Universities, 2013, 29(1): 159-165.

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