Electronic and Nano-structural Modulation of Co(OH)2 Nanosheets by Fe-Benzenedicarboxylate for Efficient Oxygen Evolution

doi:10.1007/s40242-022-2228-1

Abstract

Abstract: Oxygen evolution reaction(OER) plays a key role in the electrochemical conversion and storage processes, but the sluggish kinetics of OER strongly impedes its large-scale applications. We herein reported the in situ growth of Fe-benzenedicarboxylate(Fe-BDC) on Co(OH)₂ nanoplates[Fe-BDC/ Co(OH)₂] that showed remarkably enhanced OER activity than the pristine Co(OH)₂. The incorporation of Fe species could enhance the intrinsic OER activity of Co and BDC could increase the electro-chemically active surface area(ECSA), thus resulting in dramatically enhanced OER activity. In situ Raman spectroscopy characterization disclosed that Fe-CoOOH reconstructed from Fe-BDC/Co(OH)₂ was the real active site for OER. This work highlights the significance of rational tailoring of the nanostructure and electronic structure of Co(OH)₂ and provides more opportunities for its widespread applications.

Key words: Co(OH)₂ nanoplate, Oxygen evolution reaction, Electronic structure, Nanostructure, In situ Raman spectroscopy

XIAO Long, WU Huirong, ZHANG Yong, SUN Hao, ZHANG Wenchao, LYU Fenglei, DENG Zhao, PENG Yang. Electronic and Nano-structural Modulation of Co(OH)₂ Nanosheets by Fe-Benzenedicarboxylate for Efficient Oxygen Evolution[J]. Chemical Research in Chinese Universities, 2023, 39(2): 219-223.

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Electronic and Nano-structural Modulation of Co(OH)₂ Nanosheets by Fe-Benzenedicarboxylate for Efficient Oxygen Evolution

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