Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts

doi:10.1007/s40242-019-8390-4

Abstract

Abstract: Reductive amination of aldehydes/ketones with aqueous NH₃ and hydrogenation of nitriles to primary amines with Co catalysts were reported. Co@NC-700 exhibited remarkable activity and high selectivity for the reductive amination of aldehydes/ketones with aqueous NH₃ and the hydrogenation of nitriles to primary amines. Several primary amines can be obtained with good to excellent yields via the reductive amination of aldehydes/ketones and the hydrogenation of nitriles. The nitrogen-doped carbon(C)-supported Co@NC-700 metal catalyst was prepared via the pyrolysis of bioMOF Co/adenine in activated C. Co@NC-700 can be reused five times without evident loss of activity.

Key words: Primary amine, Cobalt, Reductive amination, Aldehyde, Hydrogenation, Nitrile

LIU Junmei, GUO Wanwan, SUN Hao, LI Ruyue, FENG Zhipeng, ZHOU Xuyang, HUANG Jun. Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts[J]. Chemical Research in Chinese Universities, 2019, 35(3): 457-462.

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