Chemical Research in Chinese Universities ›› 2000, Vol. 16 ›› Issue (4): 320-323.
• Articles • Previous Articles Next Articles
LI Ting-you, WANG Li-ping, CUI Wei, ZHAO Jian-zhang, WANG Zong-mu
Received:
Online:
Published:
Abstract: The reduction of TiCl4(THF)2 with Al in CH2Cl2 gave a green solution of [Ti2(μ-Cl)2Cl4· (THF)4] (1) which was found to promote the reductive homocoupling of aromatic aldehydes to yield symmetrical 1, 2-diols with high diasterepselectivities.
Key words: Pinacol coupling reaction, Aromatic aldehyde, Diastereoselectivity
LI Ting-you, WANG Li-ping, CUI Wei, ZHAO Jian-zhang, WANG Zong-mu . An Efficient System TiCl4-Al for the Homocoupling Reaction of Aromatic Aldehydes[J]. Chemical Research in Chinese Universities, 2000, 16(4): 320-323.
0 / / Recommend
Add to citation manager EndNote|Reference Manager|ProCite|BibTeX|RefWorks
URL: https://crcu.jlu.edu.cn/EN/
https://crcu.jlu.edu.cn/EN/Y2000/V16/I4/320