CRCU

Chemical Research in Chinese Universities ›› 2000, Vol. 16 ›› Issue (4): 324-327.

• Articles • Previous Articles     Next Articles

Synthesis of a Soluble Diacetylene with Phenylimidazole Ring

WANG Jiang-hong1, CAO Ya-an1, CAO Chang-sheng2,3, SHI Yan-hui2, SHONG Qing2, WANG Li-jun3, YAO Jian-nian1   

  1. 1. Institute of Photographic Chemistry, Chinese Academy of Sciences, Beijing 100101, P. R. China;
    2. Department of Chemistry, Jilin University, Changchun 130023, P. R. China;
    3. Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences;Laboratory of Excited State Processes, Chinese Academy of Sciences, Changchun 130021, P. R. China
  • Received:1999-11-07 Online:2000-12-24 Published:2011-09-09
  • Supported by:

    Supported by the "95" Key Project of Chinese Academy of Sciences Specially and the National Natural ScienceFoundation of China(No. 59620167).

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Cited

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Abstract: 6-(2-Methyl-4-phenyl)-N-imidazole-2, 4-hexadiyn-1-ol was synthesized in a good yield by asymmetric coupling, and the corresponding intermediates were also prepared.The diacetylene monomer could be dissolved in common organic solvents.In addition, all kinds of conditions were also discussed effectively improving the formation of the diacetylene monomer.

Key words: Asymmetric coupling, Phenylimidazole Ring, Polydiacetylene