Two New Supramolecular Hybrids Based on Bi-capped Keggin {PMo12V2O42} Clusters and Transition Metal Mixed-organic-ligand Complexes

doi:10.1007/s40242-015-5033-2

Abstract

Abstract:

Two supramolecular compounds [Cu(imz)₂][Cu(phen)(imz)]₂{[Cu(phen)]₂[PMo₆^VIMo₆^VV₂^IVO₄₂]}(1) and [Co₂(2,2'-bpy)₄(C₂O₄)][Co(2,2'-bpy)₃][PMo₇^VIMo₅^VV₂^IVO₄₂](2,2'-bpy)_0.5·H₂O(2)(phen=1,10'-phenanthroline, imz= imidazole, 2,2'-bpy=2.2'-bipyridine) have been synthesized hydrothermally and characterized by elemental analyses, infrared spectrum, UV-Vis, X-ray photoelectron spectroscopy(XPS), electron spin resonance(ESR) spectra, thermogravimetry analyses and single crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses revealed that both the compounds represent the examples of compounds based on the bi-capped Keggin polyoxoanion {PMo₁₂V₂O₄₂} and transition metal mixed-organic-ligand coordination complexes. Compound 1 consists of bi-capped Keggin polyoxoanion [PMo₁₂V₂O₄₂]^5- supported copper coordination groups, which are further inter- connected with two types of copper complex fragments forming a 3D supramolecular framework via π…π stacking, C—H…O and N—H…O hydrothermal bonding interactions. Compound 2 is a new hybrid consisted of polyoxoanion [PMo₁₂V₂O₄₂]^4-, [Co₂(2,2'-bpy)₄(C₂O₄)]²⁺ and [Co(2,2'-bpy)₃]²⁺. There are no direct interactions in compound 2, but the polyoxoanions together with two different cobalt complex groups construct a 3D supramolecular network through C—H…O hydrogen bonding interactions.

Key words: Transition metal mixed-organic-ligand complex, Keggin polyoxometalate, Hydrogen bond, π…&pi, Stacking interaction

DUAN Weijie, JIAO Shihui, LIU Xu, CHEN Jinlei, CAO Xuan, CHEN Yan, XU Wei, CUI Xiaobing, XU Jiqing, PANG Guangsheng. Two New Supramolecular Hybrids Based on Bi-capped Keggin {PMo₁₂V₂O₄₂} Clusters and Transition Metal Mixed-organic-ligand Complexes[J]. Chemical Research in Chinese Universities, 2015, 31(2): 179-186.

References

[1] Lehn J. M., Supramolecular Chemistry, VCH, New York, 1995
[2] Vögtle F., Supramolecular Chemistry, Wiley, Chichester, 1991
[3] Lehn M., Comprehensive Supramolecular Chemistry, Pergamum, New York, 1996
[4] Lehn J. M., Angew. Chem. Int. Ed. Eng., 1990, 29, 1304
[5] Kolotuchin S. V., Fenlon E. E., Wilson S. R., Loweth C. J., Zimmerman S. C., Angew. Chem. Int. Ed., 1995, 34, 2654
[6] Lehn J. M., Science, 2002, 295, 2400
[7] Holliday B. J., Mirkin C. A., Angew. Chem. Int. Ed., 2001, 40, 2022
[8] Eddaoudi M., Moler D. B., Li H., Chen B., Reineke T. M., O'Keeffe M., Yaghi O. M., Acc. Chem. Res., 2001, 34, 319
[9] Tian A. X., Lin X. L., Liu Y. J., Liu G. Y., Ying J., Wang X. L., Lin H. Y., J. Coord. Chem., 2012, 65, 2417
[10] Wei M. L., Li H. H., He G. J., J. Coord. Chem., 2012, 65, 4318
[11] Pope M. T., Heteropoly and Ispoly OXometalates, Spring-Verlag, Berlin, 1983
[12] Hill C., Chem. Rev., 1998, 98, 1
[13] Müller A., Koop M., Schiffels P., Bögge H., Chem. Commun., 1997, (18), 1715
[14] Long D. L., Tsunashima R., Cronin L., Angew. Chem. Int. Ed. Eng., 2010, 49, 1736
[15] Xu Y., Zhu H. G., Cai H., You X. Z., Chem. Commun., 1999, (9), 787
[16] Burkholder E., Zubieta J., Chem. Commun., 2001, (20), 2056
[17] Khan M. L., Cevik S., Hayashi R., J. Chem. Soc. Dalton Trans., 2002, 14, 2879
[18] Streb C. D., Long L., Cronin L., CrystEngCommun, 2006, 8, 629
[19] Cheng D. P., Khan M. A., Houser R. P., Inorg. Chem., 2001, 40, 6858
[20] Sun D. F., Cao R., Sun Y. Q., Bi W. H., Li X. J., Wang Y. Q., Shi Q., Li X., Inorg. Chem., 2003, 42, 7512
[21] Kumagai H., Arishima M., Kitagawa S., Ymada K., Kawata S., Kaizaki S., Inorg. Chem., 2002, 41, 1989
[22] Duan W. J., Cui X. B., Xu Y., Xu J. Q., Yu H. H., Yi Z. H., Cui J. W., Wang T. G., J. Solid State Chem., 2007, 180, 1875
[23] Liu Y. B., Duan L. M., Yang X. M., Xu J. Q., Zhang Q. B., Lu Y. K., Liu J., J. Solid State Chem., 2006, 179, 122
[24] Shringarpurea P., Tripuramallub B. K., Patel K., J. Coord. Chem., 2012, 64, 4016
[25] Kong Q. J., Hu M. X., Chen Y. G., J. Coord. Chem., 2012, 65, 3237
[26] Davis M. E., Nature, 2002, 417, 813
[27] Mizuno N., Misono M., Chem. Rev., 1998, 98, 199
[28] Thiel J., Molina P. I., Symes M. D., Cronin L., Cryst. Growth Des., 2012, 12, 902
[29] Wutkowski A., Srinivasan B. R., Naik A. R., Schütt C., Näther C., Bensc W., Eur. J. Inorg. Chem., 2011, 2254
[30] Liu C. M., Luo J. L., Zhang D. Q., Wang N. L., Chen Z. J., Zhu D. B., Eur. J. Inorg. Chem., 2004, 4774
[31] Liu Y. B., Duan W. J., Cui X. B., Xu J. Q., Chem. Res. Chinese Universities, 2015, 31(1), 4
[32] Sha J. Q., Peng J., Tian A. X., Liu H. S., Chen J., Zhang P. P., Su Z. M., Cryst. Growth Des., 2007, 7, 2535
[33] Xiao L. N., Peng Y., Wang Y., Xu J. N., Gao Z. M., Liu Y. B., Zheng D. F., Cui X. B., Xu J. Q., Eur. J. Inorg. Chem., 2011, 12, 1997
[34] Liu C. M., Zhang D. Q., Zhu D. B., Cryst. Growth Des., 2006, 6, 524
[35] Liu C. M., Zhang D. Q., Xiong M., Zhu D. B., Chem. Commun., 2002, 1416
[36] Shi S. Y., Pan C. L., Chen Y., Xu J. N., Cui X. B., Wang Y., Xu J. Q., Inorg. Chem. Commun., 2009, 12, 1124
[37] Pan C. L., Xu J. Q., Sun Y., Chu D. Q., Ye L., Lü Z. L., Wang T. G., Inorg. Chem. Commun., 2003, 6, 233
[38] Duan L. M., Pan C. L., Xu J. Q., Cui X. B., Xie F. T., Wang T. G., Eur. J. Inorg. Chem., 2003, 2578
[39] Shi Z. Y., Gu X. J., Peng J., Xu Y., Wang E. B., Eur. J. Inorg. Chem., 2006, 385
[40] Niu J. Y., Chen G., Zhao J. W., Yu C. F., Ma P. T., Wang J. P., Cryst. Growth Des., 2010, 10, 4689
[41] Wang L. M., Wang Y., Fan Y., Xiao L. N., Hu Y. Y., Gao Z. M., Zheng D. F., Cui X. B., Xu J. Q., CrystEngComm, 2014, 16, 430
[42] Lu Y. K., Cui X. B., Xu J. N., Gao Q., Chen Y., Jin J., Shi S. Y., Xu J. Q., Wang T. G., J. Coord. Chem., 2010, 63, 394
[43] Shi Z. Y., Gu X. J., Peng J., Wang E. B., J. Mole. Struct., 2005, 737, 147
[44] Xu Y., Zhu D. R., Song Y., Zheng X. F., You X. Z., J. Mole. Struct., 2006, 782, 165
[45] Himeno S., Takamoto M., Higuchi A., Maekawa M., Inorg. Chem. Acta, 2003, 348, 57
[46] Ritchie C., Burkholder E., Kögerlerb P., Cronin I., Dalton Trans., 2006, 1712
[47] Reinoso S., Vitoria P., Lezama L., Luque A., Gutirrez-Zorrilla J. M., Inorg. Chem., 2003, 42, 3709
[48] Yuan L., Qin C., Wang X. L., Wang E. B., Chang S., Eur. J. Inorg. Chem., 2008, 4936
[49] Tao J., Zhang X. M., Tong M. L., Chen X. M., Dalton Trans., 2001, 770
[50] Reinoso S., Vitoria P., Felices L., Lezama L., Gutirrez-Zorrilla J. M., Inorg. Chem., 2006, 45, 108
[51] Le Y., Dong B. X., Peng J., Zhang S. Y., Song L., Ge J., CrystEngComm, 2013, 15, 2783
[52] Sheldrick G. M., SHELXL-97, University of Göttingen, Göttingen, 1997
[53] Feng S. H., Xu R. R., Acc. Chem. Res., 2001, 34, 239
[54] Altermatt D., Brown I. D., Acta Crystallogr. B, 1985, 41, 240
[55] Rocchiccioli-Deltcheff C., Fournier M., Franck R., Thouvenot R., Inorg. Chem., 1983, 22, 207
[56] Sheckelton J. P., Neilson J. R., Soltan D. G., McQueen T. M., Nature Materials, 2012, 11, 493
[57] Bridges C. A., Hansen T., Wills A. S., Luke G. M., Greedan J. E., Phys. Rev. B, 2006, 74, 024426

Two New Supramolecular Hybrids Based on Bi-capped Keggin {PMo₁₂V₂O₄₂} Clusters and Transition Metal Mixed-organic-ligand Complexes

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	ZHANG Bingyi, ZHANG Xiaolei, SU Ruochen, SUN Yue and DUAN Lian. ESIPT-regulated Mechanoresponsive Luminescence Process by Introducing Intramolecular Hydrogen Bond in Naphthalimide Derivatives#br# [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1050-1056.
[2]	QU Huiqi, PAN Longhai, SUN Yuexin, WANG Lei, LI Yanyan, ZHANG Mingjuan, ZHANG Zhaoxiang, LIN Haifeng. Supramolecular Assemblies of Three New Metronidazole Derivatives Constructed with Various Dihydroxy-benzoic Acids via Hydrogen Bonds [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1196-1202.
[3]	TIAN Jinmiao, CHEN Sikai, WANG Xiang, LI Juan. Evolution of Artificial Base Pairs with Hydrogen Bond Complementarity [J]. Chemical Research in Chinese Universities, 2020, 36(2): 151-156.
[4]	SHI Peijun, ZHANG Zhe, LIU Mingchun, SUN Teng, HE Xiaoyan, MAO Chengde, FANG Liang, ZUO Hua. Increasing the Solubility of a Hydrophobic Molecule with Thymine-like Face by DNA via Supramolecular Interaction [J]. Chemical Research in Chinese Universities, 2020, 36(2): 281-284.
[5]	YU Wenli, ZHANG Mingjuan, LIU Kang, YANG Yu, WANG Lei. Hydrogen Bonding Assembled 3D Supramolecular Structures Formed by 5-Amino-2,4,6-triiodoisophthalic Acid and N-Heterocyclic Aromatic Ligands [J]. Chemical Research in Chinese Universities, 2019, 35(5): 806-811.
[6]	LU Zhiyi, TANG Liming. Modulation of Supramolecular Interactions of Urea-based Supramolecular Polymers via Molecular Structures [J]. Chemical Research in Chinese Universities, 2018, 34(5): 849-856.
[7]	ZHANG Hongmei, LIU Yan, MA Fangping, QIU Wei, LEI Bo, SHEN Jinyou, SUN Xiuyun, HAN Weiqing, LI Jiansheng, WANG Lianjun. Density Functional Theoretical Studies on Effect of Intramolecular Hydrogen Bonds on Reduction of Nitrophenols [J]. Chemical Research in Chinese Universities, 2017, 33(5): 785-793.
[8]	ZHAO Meng, CHEN Hanfei, GU Fang, WANG Haijun. Structure of Solution of Colloid and Hydrogen Bonding Fluid Near a Semipermeable Membrane [J]. Chemical Research in Chinese Universities, 2017, 33(2): 248-254.
[9]	HUANG Cuiying, HAO Qiang, WANG Changsheng. Rapid Prediction of Interaction Energies for Nucleoside-containing Hydrogen-bonded Complexes: Lone-pair Dipole Moment Treatment for Adenine, Cytosine and Guanine [J]. Chemical Research in Chinese Universities, 2017, 33(1): 94-99.
[10]	LÜ Lei, MU Bao, LI Na, HUANG Rudan. Synthesis, Structures and Properties of Three New Compounds Based on Multidentate Ligand Containing Triazole and Pyrimidine [J]. Chemical Research in Chinese Universities, 2015, 31(5): 712-718.
[11]	WU Yichao, DENG Xiuqing, MAO Yinchun, ZHANG Yan, LIU Jiaqin, RONG Li, XU Zhihong. Retention Mechanism of Phenolic Compounds in Subcritical Water Chromatography [J]. Chemical Research in Chinese Universities, 2015, 31(1): 103-106.
[12]	YANG Yu, XU Wenyan, HU Yanjing, WANG Lei, HUANG Keke. Multi-component Hydrogen-bonding Organic Salts Formed from 1-Methylpiperazine with Aromatic Carboxylic Acids: Synthons Cooperation and Crystal Structures [J]. Chemical Research in Chinese Universities, 2015, 31(1): 9-15.
[13]	LI Yu, JIANG Long. Solvent Effect on Characteristic Vibration of IR Spectrum of 4,4'-Dibromodiphenyl Ether [J]. Chemical Research in Chinese Universities, 2014, 30(6): 997-1004.
[14]	MA Jie, WEI Jue, BAI Binglian, TAN Guangtong, WANG Haitao, LI Min. Direct Evidence for the Effect of Intermolecular Hydrogen Bonding on Organogels [J]. Chemical Research in Chinese Universities, 2014, 30(5): 821-824.
[15]	LI Li, BAI Fuquan, ZHANG Hongxing. Theoretical Studies on the Dihydrogen Bonding Between Shortchain Hydrocarbon and Magnesium Hydride [J]. Chemical Research in Chinese Universities, 2014, 30(5): 831-836.