A Novel, Efficient and Facile Method for the Template Removal from Mesoporous Materials

doi:10.1007/s40242-014-4202-z

Chemical Research in Chinese Universities ›› 2014, Vol. 30 ›› Issue (6): 894-899.doi: 10.1007/s40242-014-4202-z

• Articles • Previous Articles Next Articles

A Novel, Efficient and Facile Method for the Template Removal from Mesoporous Materials

CHEN Lu^1,2, JIANG Shang¹, WANG Runwei¹, ZHANG Zongtao¹, QIU Shilun¹

1. State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130012, P. R. China;
2. College of Chemistry and Biology, Beihua University, Jilin 132013, P. R. China

Received:2014-05-26 Revised:2014-09-01 Online:2014-12-01 Published:2014-09-15
Contact: WANG Runwei E-mail:rwwang@jlu.edu.cn
Supported by:
Supported by the National Basic Research Program of China(Nos.2011CB808703, 2012CB821700), the National Natural Science Foundation of China(Nos.91022030, 21261130584), the Programme of Introducing Talents of Discipline to Universities of China(No.B07016), the Award Project of King Abdullah University of Science Technology of Saudi Arabia (No.CRG-1-2012-LAI-009) and the Science and Technology Development Center Project of Ministry of Education of China(No.20120061130012).

Abstract

Abstract:

A new catalytic-oxidation method was adopted to remove the templates from SBA-15 and MCM-41 mesoporous materials via Fenton-like techniques under microwave irradiation. The mesoporous silica materials were treated with different Fenton agents based on the template's property and textural property. The samples were characterized by powder X-ray diffraction(XRD) measurement, N₂ adsorption-desorption isotherms, infrared spectro- scopy, ²⁹Si MAS NMR and thermo gravimetric analysis(TGA). The results reveal that this is an efficient and facile approach to the thorough template-removal from mesoporous silica materials, as well as to offering products with more stable structures, higher BET surface areas, larger pore volumes and larger quantity of silanol groups.

Key words: Detemplation, Mesoporous silica material, Fenton technique, Microwave, Hydrogen peroxide

CHEN Lu, JIANG Shang, WANG Runwei, ZHANG Zongtao, QIU Shilun. A Novel, Efficient and Facile Method for the Template Removal from Mesoporous Materials[J]. Chemical Research in Chinese Universities, 2014, 30(6): 894-899.

References

[1] Beck J. S., Vartuli J. C., Roth W. J., Leonowicz M. E, Kresge C. T., Schmitt K. D., Chu C. T. W., Olson D. H., Sheppard E. W., McCullen S. B., Higgins J. B., Schlenkert J. L., J. Am. Chem. Soc., 1992, 114, 10834
[2] Zhao D. Y., Feng J. L., Huo Q. S., Melosh N., Fredrickson G. H., Chmelka B. F., Stucky G. D., Science, 1998, 279, 548
[3] Vallet-Regí M., Balas F., Arcos D., Angew. Chem. Int. Ed., 2007, 46, 7548
[4] Gallis K. W., Landry C. C., Adv. Mater., 2001, 13, 23
[5] Tang D. H., Zhang W. R., Wang Y. F., Miao J., Qiao Z. A., Huo Q. S., Zhang L. R., Chem. Res. Chinese Universities, 2014, 30(3), 531
[6] Rao Y. V. S., Vos D. E. D., Jacobs P. A., Angew. Chem. Int. Ed., 1997, 36, 2661
[7] He J., Yang X. B., Evans D. G., Duan X., Mater. Chem. Phys., 2003, 77, 270
[8] Hitz S., Prins R., J. Catal., 1997, 168, 194
[9] Huang L., Poh C., Ng S. C., Hidajat K., Kawi S., Langmuir, 2005, 21, 1171
[10] Yang C. M., Zibrowius B., Schmidt W., Schüth F., Chem. Mater., 2004, 16, 2918
[11] Grudzien R. M., Grabicka B. E., Jaroniec M., J. Mater. Chem., 2006, 16, 819
[12] Aleboyeh A., Olya M. E., Aleboyeh H., Chem. Eng. J., 2008, 137, 518
[13] Legrini O., Oliveros E., Braun A. M., Chem. Rev., 1993, 93, 671
[14] Hozumi A., Yokogawa Y., Kameyama T., Hiraku K., Sugimura H., Takai O., Okido M., Adv. Mater., 2000, 12, 985
[15] Büchel G., Denoyel R., Llewellyn P. L., Rouquerol J., J. Mater. Chem., 2001, 11, 589
[16] Keene M. T. J., Denoyel R., Llewellyn P. L., Chem. Commun., 1998, 2203
[17] Xiao L. P., Li J. Y., Jin H. X., Xu R. R., Micropor. Mesopor. Mater., 2006, 96, 413
[18] Xia Y. D., Mokaya R., J. Phys. Chem. B, 2006, 110, 9122
[19] Melián-Cabrera I., Kapteijn F., Moulijn J. A., Chem. Commun., 2005, 2744
[20] Maurya M. R., Titinchi S. J. J., Chand S., Mishra I. M., J. Mol. Catal. A: Chem., 2002, 180, 201
[21] Zhao D. Z., Jing S. B., Xu J. N., Yang H., Zheng W., Song T. Y., Zhang P., Chem. Res. Chinese Universities, 2013, 29(4), 793
[22] Kleitz F., Schmidt W., Schüth F., Micropor. Mesopor. Mater., 2001, 44/45, 95
[23] Xiang Q. J., Yu J. G., Wong P. K., J. Colloid Interf. Sci., 2011, 357, 163
[24] Sanz J., Lombraña J. I., de Luis A.M., Ortueta M., Varona F., Environ. Chem. Lett., 2003, 1, 45
[25] Huo Q. S., Margolese D. I., Ciesla U., Feng P., Gier T. E., Sieger P., Leon R., Petroff P. M., Schuth F., Stucky G. D., Nature, 1994, 368, 317
[26] Cotton F. A., Wilkinson G., Advanced Inorganic Chemistry, Inter- science Publishers(a Division of John Wiley&Sons), New York, 1962, 36
[27] Zhao D. Y., Huo Q. S., Feng J. L., Chmelka B. F., Stucky G. D., J. Am. Chem. Soc., 1998, 120, 6024

A Novel, Efficient and Facile Method for the Template Removal from Mesoporous Materials

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	LIU Yifeng, WANG Liang, and XIAO Feng-Shou. Selective Oxidation of Methane into Methanol Under Mild Conditions [J]. Chemical Research in Chinese Universities, 2022, 38(3): 671-676.
[2]	YAN Liuqing, FU Jiaxu, LI Shuang, ZHANG Jinlong, WANG Shuang, GU Qiang, ZHANG Yumin, LIN Feng. Microwave-assisted Catalyzed Synthesis and In vitro Bioactivity Evaluation of Benzimidazoles Bearing Phenolic Hydroxyl [J]. Chemical Research in Chinese Universities, 2021, 37(3): 639-646.
[3]	YU Fangyuan, WANG Kai, WANG Chuan, HE Xinxia, LIAO Yang, ZHAO Shilin, MAO Hui, LI Xiaoting, MA Jun. Anthraquinone Covalently Modified Carbon Nanotubes for Efficient and Steady Electrocatalytic H₂O₂ Generation [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1332-1338.
[4]	LI Guijie, LIU Chang, LIU Hongcheng, WANG Dawei, DING Lan. Dynamic Microwave-assisted Extraction Online Coupled with QuEChERS for the Determination of Organophosphorus Pesticides in Cereals by Gas Chromatography [J]. Chemical Research in Chinese Universities, 2020, 36(5): 768-773.
[5]	LI Long, HUANG Yan, ZHAO Pei, MIAO Haochi, ZHAO Ting. Deep Eutectic Solvent-assisted Synthesis of Nitrogen-doped Carbon Quantum Dots for Cell Imaging [J]. Chemical Research in Chinese Universities, 2020, 36(5): 955-961.
[6]	SHI Yanpeng, CHEN Xiaodong, MI Zhiming, ZHENG Ran, FAN Jie, GU Qiang, ZHANG Yumin. A New Tetrasubstituted Imidazole Based Difunctional Probe for UV-spectrophotometric and Fluorometric Detecting of Fe³⁺ Ion in Aqueous Solution [J]. Chemical Research in Chinese Universities, 2019, 35(2): 200-208.
[7]	YANG Xiufang, WANG Xiaogang, WANG Tingting, WANG Weitao, ZHANG Jin, MA Yangmin. A Highly Efficient and Recyclable Solid Acid Catalyst for Synthesis of Spiro-oxindole Dihydroquinazolinones Under Ultrasound Irradiation [J]. Chemical Research in Chinese Universities, 2019, 35(1): 33-40.
[8]	JIANG Zhenlei, LIU Jie, ZHOU Fan, ZHANG Jianrun, LIU Zhijun, ZHANG Chao, CHEN Heru. One-step Construction of Xanthone Scaffold Assisted by Microwave Irradiation to Optimize the Synthesis of DMXAA [J]. Chemical Research in Chinese Universities, 2018, 34(6): 918-922.
[9]	LI Guijie, LIU Chang, WANG Dawei, DING Lan. Eco-friendly and Cleaner Process Using Online Microwave-assisted Steam Extraction Coupled with Solid-phase Extraction for Trace Analysis of Sulfonamides in Animal Feed [J]. Chemical Research in Chinese Universities, 2018, 34(6): 893-898.
[10]	HAN Xie, SHAO Kaiyuan, HU Wenxiang. Synthesis of 9-Substituted Berberine Derivatives with Microwave Irradiation [J]. Chemical Research in Chinese Universities, 2018, 34(4): 571-577.
[11]	MI Zhiming, CHEN Yao, CHEN Xiaodong, YAN Liuqing, GU Qiang, ZHANG Hanqi, CHEN Chunhai, ZHANG Yumin. Synthesis of Highly Sensitive Fluorescent Probe Based on Tetrasubstituted Imidazole and Its Application for Selective Detection of Ag⁺ Ion in Aqueous Media [J]. Chemical Research in Chinese Universities, 2018, 34(3): 369-374.
[12]	REN Hejun, MA Taigang, ZHAO Jian, ZHOU Rui. V_c-Functionalized Fe₃O₄ Nanocomposites as Peroxidase-like Mimetics for H₂O₂ and Glucose Sensing [J]. Chemical Research in Chinese Universities, 2018, 34(2): 260-268.
[13]	LI Jing, LIU Hongwei, MENG Fanyu, YAN Liuqing, SHI Yanpeng, ZHANG Yumin, GU Qiang. Microwave-assisted Synthesis of New 1,2,3-Triazoles Bearing an Isoxazole Ring by the Azide-alkyne Cycloaddition Click Chemistry [J]. Chemical Research in Chinese Universities, 2018, 34(2): 197-202.
[14]	ZHU Dan, JIN Wei, YU Bingwen, YING Yangwei, YU Haixiang, SHAN Jin, YAN Yuwei, XU Chen, WANG Baolai, JIN Qinhan. Development of a Novel Kilowatt Microwave Plasma Torch Source for Atomic Emission Spectrometry [J]. Chemical Research in Chinese Universities, 2017, 33(5): 709-713.
[15]	WANG Aijuan, DUAN Yuzhe, GU Xiaoyu, ZHANG Sheng, ZANG Wenhui. Surface Modification of Polyamide66 Fabric by Grafting with Vinyltrimethoxysilane [J]. Chemical Research in Chinese Universities, 2017, 33(3): 492-498.