Structure Analysis of Needle-like Copper Tantalum Trisulfide Crystals by XPS and Raman Spectroscopy

Chemical Research in Chinese Universities ›› 2012, Vol. 28 ›› Issue (2): 171-175 .

• Articles • Previous Articles Next Articles

Structure Analysis of Needle-like Copper Tantalum Trisulfide Crystals by XPS and Raman Spectroscopy

CHENG Dan, JIN Hua, LI Ben-xian, WANG Xiao-feng, CHU Qing-xin, Lü Yang, LIU Xiao-yang, ZHAO Xu-dong

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2011-03-11 Revised:2011-04-07 Online:2012-03-25 Published:2012-03-08
Supported by:
Supported by the National Natural Science Foundation of China(Nos.20471022, 40673051 and 20121103) and the Program for New Century Excellent Talents(NCET) in Universities of China.

Abstract

Abstract: High-quality needle-like CuTaS3 single crystals have been synthesized through a chemical vapor transport(CVT) process. Crystallographic data show the special double chains of edge-sharing TaS₆ octahedra. The detailed XPS analysis of CuTaS₃ was undertaken and the valence states can be described by Cu⁺Ta⁵⁺3S^2–. In addition, CuTaS₃ crystals were characterized with Raman spectroscopy.

Key words: Cu-Ta-S compound, Ta₂S₁₀ dimeric chain, X-Ray photoelectron spectroscopy, Raman spectrum

CHENG Dan, JIN Hua, LI Ben-xian, WANG Xiao-feng, CHU Qing-xin, Lü Yang, LIU Xiao-yang, ZHAO Xu-dong. Structure Analysis of Needle-like Copper Tantalum Trisulfide Crystals by XPS and Raman Spectroscopy[J]. Chemical Research in Chinese Universities, 2012, 28(2): 171-175 .

References

[1] Wada H., Nozaki H., Sato A., Takada K., Sasaki T., J. Alloys Compd., 2004, 383, 148 [2] Valant M., Kolodiazhnyi T., Axelsson A. K., Babu G. S., Alford N. M., Chem. Mater., 2010, 22, 1952 [3] Mann M., Jackson S., Kolis J., J. Solid State Chem., 2010, 183, 2675 [4] Zhu X. D., Sun Y. P., Zhang S. B., Lei H. C., Li L. J., Zhu X. B., Yang Z. R., Song W. H., Dai J. M., Solid State Commun., 2009, 149, 1296 [5] Wu X. C., Tao Y. R., Gao Q. X., Mao C. J., Zhu J. J., Chem. Commun., 2009, 4290 [6] Wagner K. E., Morosan E., Hor Y. S., Tao J., Zhu Y., Sanders T., McQueen T. M., Zandbergen H. W., Williams A. J., West D. V., Cava R. J., Phys. Rev. B, 2008, 78, 104520 [7] Zhu X. D., Sun Y. P., Zhang S. H., Wang J. L., Zou L. J. DeLong L. E., Zhu X. B., Luo X., Wang B. S., Li G., Yang Z. R., Song W. H., J. Phys.: Condens. Matter, 2009, 21, 145701 [8] Newhouse P. F., Hersh P. A., Zakutayev A., Richard A., Platt H. A. S., Keszler D. A., Tate J., Thin Solid Films, 2009, 517, 2473 [9] Sunshine S. A., Ibers J. A., Acta Cryst., 1987, C43, 1019 [10] Squattrito P. J., Swepston P. N., Ibers J. A., Inorg. Chem., 1987, 26, 1187 [11] Sheldrick G. M., Acta Cryst., 2008, 64, 112 [12] Babo J. M., Schleid T., Solid State Sci., 2010, 12, 238 [13] Stoll P., Dürichen P., Nuther C., Bensch W., Z. Anorg. Allg. Chem., 1998, 624, 1807 [14] Wada H., Sato A., Nozaki H., J. Alloys Compd., 2001, 317/318, 217 [15] Keane P. M., Ibers J. A., J. Solid State Chem., 1991, 93, 291 [16] Klepp K. O., Gurtner D., J. Alloys Compd., 1996, 239, 1 [17] Poudeu P. F. P., Takas N., Anglin C., Eastwood J., Rivera A., J. Am. Chem. Soc., 2010, 132, 5751 [18] Krylova V., Andrulevicius A., Int. J. Photoenergy, 2009, 2009, 304308 [19] Carniato S., Dufour G., Luo Y., Agren H., Phys. Rev. B, 2002, 66, 045105 [20] Yang F., Ji T. H., Du H. Y., Sun J. Y., Yang Q. Li, Ge G. L., Chem. Res. Chinese Universities, 2009, 25(2), 132 [21] Zhong H. Z., Zhou Y., Ye M. F., He Y. J., Ye J. P., He C., Yang C., Li Y. F., Chem. Mater., 2008, 20, 6434 [22] Gutzmann A., Nather C., Bensch W., Inorg. Chem., 2004, 43, 2998 [23] Peters E. S., Carmalt C. J., Parkin I. P., Tocher D. A., Eur. J. Inorg. Chem., 2005, 4179 [24] Lamour P., Fioux P., Ponche A., Nardin M., Vallat M. F., Dugay P., Brun J. P., Moreaud N., Pinvidic J. M., Surf. Interface Anal., 2008, 40, 1430 [25] Kuhn M., Sammynaiken R., Sham T. K., Physica B, 1998, 252, 114 [26] Yang D. H., Jiang H., Ott R., Minor K., Grant J., Varga L., Barnard J. A., Doyle W. D., Surf. Interface Anal., 1999, 27, 259 [27] Wu Y. D., Nather C., Bensch W., J. Solid State Chem., 2005, 178, 1569 [28] Wu Y. D., Bensch W., J. Solid State Chem., 2007, 180, 2166 [29] Chen P., Cabrito I., Moura J. J. G., Moura I., Solomon E. I., J. Am. Chem. Soc., 2002, 124, 10497 [30] Kohzuma T., Kikuchi M., Horikoshi N., Nagatomo S., Kitagawa T., Czernuszewicz R. S., Inorg. Chem., 2006, 45, 8474 [31] Sokolov M. N., Gushchin A. L., Abramov P. A., Virovets A. V., Pe-resypkina E. V., Kozlova S. G., Kolesov B. A., Vicent C., Fedin V. P., Inorg. Chem., 2005, 44, 8756

Structure Analysis of Needle-like Copper Tantalum Trisulfide Crystals by XPS and Raman Spectroscopy

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 7

Recommended Articles

Metrics

Comments

[1]	SHANG Yongbin, XIAO Shuqin, QIU Xiaolin, WEI Yaming. Influence of Cr on the Electronic Properties of Passive Film on B30 Alloy in NaOH Solution [J]. Chemical Research in Chinese Universities, 2015, 31(4): 603-610.
[2]	LIANG Xiao-juan, ZHONG Jia-song, CAI Qian, HUANG Hai-yu, LIU Hai-tao, XIANG Wei-dong, SUN Jun-cai. L-Cysteine-assisted Synthesis of Copper Gallium Sulfide Microspheres [J]. Chemical Research in Chinese Universities, 2012, 28(3): 395-398.
[3]	LI Dang-guo, CHEN Da-rong*, WANG Jia-dao and CHEN Hao-sheng. Investigation on Semi-conductive Properties of Hot Growth Film on 316L Austenitic Stainless Steel [J]. Chemical Research in Chinese Universities, 2011, 27(4): 697-702.
[4]	SHI Xiu-min, WANG Hai-yan, LI Yan-bing, YANG Jing-xiu, CHEN Lei, HUI Ge, XU Wei-qing and ZHAO Bing*. Spectroscopic Studies on Co(II), Ni(II), Zn(II) Complexes with 4,4'-Bipyridine [J]. Chemical Research in Chinese Universities, 2010, 26(6): 1011-1015.
[5]	YAN Yu-xi, MU Ying, FENG Guo-dong, ZHANG Lei, ZHU Lin-lin, XU Ling, YANG Rui , JIN Qin-han . Novel Strategy for Synthesis of High Quality CdTe Nanocrystals in Aqueous Solution [J]. Chemical Research in Chinese Universities, 2008, 24(1): 8-14.
[6]	DING Zhan-hui, YAO Bin, MA Hong-an, JIA Xiao-peng, QIU Li-xia, SU Wen-hui. Raman Scattering of Nanocrystalline δ-TiN_x Synthesized by Mechanical Milling [J]. Chemical Research in Chinese Universities, 2005, 21(4): 489-491.
[7]	CUI Ai-li, GE Xu-dong, HU Yong-qi, JIN Yong, WANG Xiao-hui . Studies on the Lanthanum-Modified Lead Titanate Ultrafine Particles by Raman Spectroscopy [J]. Chemical Research in Chinese Universities, 1998, 14(2): 184-187.