Influence of Cr on the Electronic Properties of Passive Film on B30 Alloy in NaOH Solution

doi:10.1007/s40242-015-4469-8

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (4): 603-610.doi: 10.1007/s40242-015-4469-8

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Influence of Cr on the Electronic Properties of Passive Film on B30 Alloy in NaOH Solution

SHANG Yongbin¹, XIAO Shuqin^2,3, QIU Xiaolin^2,3, WEI Yaming^2,3

1. Xi'an Changqing Technology & Engineering Co., Ltd., Xi'an 710018, P. R. China;
2. Oil & Gas Technology Institute, Changqing Oil Field Company, Xi'an 710018, P. R. China;
3. National Engineering Laboratory for Exploration and Development of Low-permeability Oil & Gas Fields, Xi'an 710018, P. R. China

Received:2014-12-05 Revised:2015-04-29 Online:2015-08-01 Published:2015-05-25
Contact: SHANG Yongbin E-mail:ctec-syb@cnpc.com.cn
Supported by:
Supported by the Project of Enhanced Oil Recovery of Ground Technology Research of Changqing Oilfield, China (No.2012-E23).

Abstract

Abstract:

The influence of Cr on the electronic properties of the passive film on B30 alloy in NaOH solution was studied via electrochemical impedance spectra(EIS), potentiodynamic curve and Mott-Schottky plot. The Cr doped in the passive film on B30 alloy was detected by X-ray photoelectron spectroscopy(XPS). XPS results show that Cr₂O₃ appeared on the passive film, which implied the enhanced anti-corrosion of B30 alloy. The passive film showed a p-type semi-conductive character. The acceptor density(N_A) was in an order of magnitude of 10²² cm^-3, and N_A decreased with the increment of Cr. EIS results show that the film resistance(R_f) increased with increasing the amount of Cr. The diffusion coefficient(D₀) was calculated to be in a range of 10^-16—10^-17 cm^-2/s on the basement of point defect model(PDM).

Key words: Electrochemcal impedance spectrum, X-Ray photoelectron spectroscopy, Passive film

SHANG Yongbin, XIAO Shuqin, QIU Xiaolin, WEI Yaming. Influence of Cr on the Electronic Properties of Passive Film on B30 Alloy in NaOH Solution[J]. Chemical Research in Chinese Universities, 2015, 31(4): 603-610.

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Influence of Cr on the Electronic Properties of Passive Film on B30 Alloy in NaOH Solution

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