A Study on 4,4′-Diaminobenzene Sulfonanilide(DABSA) and the Properties of Dyes Derived from DABSA

Chemical Research in Chinese Universities ›› 2001, Vol. 17 ›› Issue (1): 77-87.

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A Study on 4,4′-Diaminobenzene Sulfonanilide(DABSA) and the Properties of Dyes Derived from DABSA

WU Zu-Wang¹, WANG Li-Min¹, DAI Jian-Ying¹, WANG Shi-Rong¹, XIAO Jin-Qiu¹, LIU Xiu-Mei², HAN Xiu-Wen², ZHAO Qi², BAO Xin-He²

1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China;
2. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Dalian 116024, China

Received:1999-10-22 Online:2001-01-24 Published:2011-08-04
Supported by:
Supported by Dankong Dyestuff Foundation.

Abstract

Abstract: A single crystal of 4,4′-diaminobenzene sulfonanilide(DABSA) was determined by X-ray diffraction method. It is shown that the two benzene rings are non-planar with an angle of 55.1°. Owing to the non-planar configuration, the dyes derived from DABSA possess a lower substantivity on fiber but better permeability in substrate, the color of these azo dyes could be matched by two individual azo dyes locating on both sides of the DABSA molecule.

Key words: 4,4'-Diaminobenzene sulfonanilide, Configuration, X-ray diffraction, Non-carcinogenic substituent for benzidine, Substantivity of dye, Azo-hydrazone tautomers

WU Zu-Wang, WANG Li-Min, DAI Jian-Ying, WANG Shi-Rong, XIAO Jin-Qiu, LIU Xiu-Mei, HAN Xiu-Wen, ZHAO Qi, BAO Xin-He . A Study on 4,4′-Diaminobenzene Sulfonanilide(DABSA) and the Properties of Dyes Derived from DABSA[J]. Chemical Research in Chinese Universities, 2001, 17(1): 77-87.

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A Study on 4,4′-Diaminobenzene Sulfonanilide(DABSA) and the Properties of Dyes Derived from DABSA

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