Chemical Research in Chinese Universities ›› 1998, Vol. 14 ›› Issue (1): 65-69.

• Articles • Previous Articles     Next Articles

Thermokinetic Oscillation of a Two-step Reacting System Coupled with Thermal Conduction and Apparent Uncertainty in the Phenomenological Kinetic Measure of Unimolecular Reactions

CHEN Xiao-nan, LUO Jiu-li   

  1. Department of Chemistry, Sichuan University, Chengdu, 610064
  • Received:1996-09-03 Online:1998-01-24 Published:2011-08-17
  • Supported by:

    Supported by the National Natural Science Foundation of China.

Abstract: A nonisothermal two-step mechanism for a unimolecular reaction coupled with thermal conduction is suggested in this paper. The stability of the relevant thermokinetic steady states was investigated by means of linear stability analysis.

Key words: Two-step mechanism, Unimolecular reaction, Linear stability analysis, Thermokinetic oscillation, Thermal coupling