Chemical Research in Chinese Universities ›› 1998, Vol. 14 ›› Issue (1): 1-5.
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MENG Lu, LIU Jing-fu
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Supported by the National Natural Science Foundation of China.
Abstract: Six new polyoxometalates a-KaHbP2W15M3O62·nH2O(a+b=12, M= Ti, Zr) and KcHdP4·W30M4O112·mH2O(c+d=20; M=Al, Ga, In, Fe) were synthesized from the lacunary precursor Na12[a-P2W15O56]·24H2O and characterized by means of elemental analysis, IR spectra, 183W NMR spectra and electrochemical methods.
Key words: Substituted tungstophosphoropolyoxometalates, Dawson structure, 183W NMR, Epoxidation reaction
MENG Lu, LIU Jing-fu. Synthesis, Characterization and Catalytic Activity of Polyoxometalates Derived from α-P2W15O5612-[J]. Chemical Research in Chinese Universities, 1998, 14(1): 1-5.
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