Chemical Research in Chinese Universities ›› 1996, Vol. 12 ›› Issue (3): 280-284.

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An XPS Study of Perovskite Oxides RECr03

Kang Zhi-jian1, LI Li-ping2, WEI Quan3   

  1. Department of Chemistry, Physics and Center for Analysis and Measurement, Jilin University, Changchun, 130023
  • Received:1995-11-20 Online:1996-07-15 Published:2011-11-18
  • Supported by:

    The National Natural Science Foundation of China

Abstract: Perovskite Oxides RECr03 (RE=La, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb) were prepared by the means of solid state reaction.The measurments of XRD and XPS showed that the replacement by rare earth element lowers the binding energy(BE) of rare earth ions, compared with their sesquioxides. In the Perovskite Oxides, the BE of Cr2p3/2 increases with the decrease of ionic radius of the RE ion.The reason for the changes of BE are discussed.

Key words: RECr03, XPS, Change of binding energy