Chemical Research in Chinese Universities ›› 1996, Vol. 12 ›› Issue (1): 50-55.

• Articles • Previous Articles     Next Articles

Stereoselective Synthesis of cis-1, 2-cyclopropane Derivatives

DING Wei-yu, HAN Zi-heng, CHEN Ya-li, ZOU Yong-jun, LIU Xin   

  1. Department of Chemistry, Shanghai University, Shanghai 201800
  • Received:1995-06-17 Online:1996-01-24 Published:2011-08-17

Abstract: Carbomethoxymethylenetriphenylar 1, or its arsonium bromide in the presence of K2CO3, reacts with 2, 2-dialkyl-1, 3-dioxa-5-substituted-benzal-4, 6-dione 2 to give cis-1-methoxycarbonyl-2-aryl-6, 6-dialky-5, 7-dioxa-spiro-[2, 5]-4,8-octanadione 3 with a moderate to good yield.

Key words: Cyclopnopanation, Stereoselective synthesis, Arsenic ylide