Chemical Research in Chinese Universities ›› 1994, Vol. 10 ›› Issue (3): 185-192.

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Studies on the Glycosides in the Leaves of Oplopanax elatus NAKAI(Ⅰ)

WANG Guang-shu1, ZHAO Chun-fang1, XU Jing-da1, Tetsuya Murayama2, Masazumi Miyakoshi2, Junzo Shoji2   

  1. 1. Bethune University of Medical Sciences, Changchun, 130021;
    2. School of Pharmaceutical Sciences, Shotwa University, Tokyo, 142
  • Received:1993-12-01 Online:1994-08-24 Published:2011-08-17
  • Supported by:

    Supported by the National Natural Science Foundation of China.

Abstract: Four new saponins were isolated from the leaves of Oplopanax elatus Nakai.The structures of the four saponins, tentatively named compounds A(1), B(2), C(3) and D (4) were elucidated to be 28-O-a-L-rhamnopyranosyl (1-4)-β-D-glu-copyranosyl (1-6)-β-D-glucopyranosyl esters of betulinic acid 3-O-β-D-glucopyra-noside (1) .oleanolic acid 3-O-β-D-glucopyranoside (2), 3a, 23-dihydroxyolean-12-ene-28-Oic acid (= 3-epi-hederagenin) (3), 3β-hydroxyolean-12-ene-23-al-28-oic acid (=gypsogenin) (4), respetively.

Key words: Optopanax elatus, Triterpenoid saponin, Betulinic acid, Oleanolic acid, 3-Epihedragenin, Gypsogenin