Chemical Research in Chinese Universities ›› 1993, Vol. 9 ›› Issue (4): 329-334.
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FENG Min-hui, HE Wei-qiang, HE Yi, LIANG Zhao-xi
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Supported by the National Natural Science Foundation of China
Abstract: Toluidine blue(TB) is a good sensitizer for the polymerization of acrylnmide(AM) induced by He-Ne laser. With TB as a sensitizer and various alcoholamine as donors, the photoredox of TB and the polymerization kinetics of AM induced by He-Ne laser were investigated. It was found that either for the photoredox of TB or for the polymerization of AM, the activity of alcoholamine increases in the order of EOA<DEOA <TEOA in TB-alcoholamine sensitized system. The overall apparent kinetic equations of AM polymerization at 30℃ have been determined. In addition, the molecular weights under various conditions was measured.
Key words: He-Ne laser, Photopolymerization, Acryiamide, Toluidine blue, Alcoho-lamine
FENG Min-hui, HE Wei-qiang, HE Yi, LIANG Zhao-xi . The Photopolymerization Kinetics of Acryl amide Sensitized with Toluidine Blue-Alcoholamine Induced by He-Ne Laser[J]. Chemical Research in Chinese Universities, 1993, 9(4): 329-334.
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https://crcu.jlu.edu.cn/EN/Y1993/V9/I4/329