Chemical Research in Chinese Universities ›› 1992, Vol. 8 ›› Issue (4): 480-482.

• Articles • Previous Articles    

A Theoretical Studies on the Thermolysis Mechanism of α-Aminonitrile

HONG San-guo1, LI Fu-quan1, FU Xiao-yuan2   

  1. 1. Department of Chemistry, Jiangxi Normal University, Nanchang, 330027;
    2. Department of Chemistry, Beijing Normal University, Beijing, 100875
  • Received:1991-11-19 Online:1992-12-24 Published:2011-08-17
  • Supported by:

    Supported by the National Natural Science Foundation of China;JiangxiProvince

Abstract: Introduction α-Aminonitrile(or aminoacetonitrile) is a kind of reactive bioorganic molecules, and it may exist in insterstellar clouds. its importance lies in that a-aminonitrile may play a role in the generation of large carbon-nitrogen chain molecules. By means of flash vacuum thermolysis and gas-solid reaction (FVT-GSR) tech-nique, Guillemin, et al., studied the thermolysis of a-aminonitrile.

Key words: Thermolysis, α-Aminonitrile, Transition state, IRC path