Synthesis and Structure of Dibenzoyl-bissemicarbazone Neodymium(Ⅲ) Perchlorate

Abstract

Abstract: A new Schiff base Dibenzoyl-bissemicarbazone C₁₅H₁₆N₆O₂(L) and its complex with neodymium(Ⅲ ) perchlorate [NdC(H₂O)₂₄)₃3.The final standard deviation R=0.0919.In the complex Nd is coordinated by four nitrogen and six oxygen atoms, of which four nitrogen and four oxygen atoms are provided by two neutral ligands L, and the other two oxygen atoms are provided by two water molecules, forming a ten-coordinated complex cation, which the perchlorate groups exist in the outer sphere.The coordination polyhedron takes a bicapped anti-square prism arrangement.

Key words: Dibenzoyl-bissemicarbazone, Schiff base, Single crystal X-ray diffraction

Huang Ling, Huang Chunhui, Xu Guangxian, Zheng Qitai, He Cunheng. Synthesis and Structure of Dibenzoyl-bissemicarbazone Neodymium(Ⅲ) Perchlorate[J]. Chemical Research in Chinese Universities, 1989, 5(4): 282-287.

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Synthesis and Structure of Dibenzoyl-bissemicarbazone Neodymium(Ⅲ) Perchlorate

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