Photoacoustic Spectrometry Investigation and Determination of Rare Earth Ions Ho3+ and Nd3+ in a Solution

Abstract

Abstract: A home-made high sensitive photoacoustic transducer was used to determine the photoacoustic signal in a solution. The photoacoustic spectra of Ho³⁺ in different solvents were measured and comparedwith its absorption spectrum. The affection factors of photoacousticsensitivity are discussed. The trivalent rare earth ions Ho³⁺ and Nd³⁺ in an aqueous acetonitrile solution were determined. The detection limit is 5×10^-8 mol/L for Ho³⁺ and 1.0 ×10^-7 mol/L for Nd³⁺, and corresponds to the absorbance of 1.5×10^-7 and 6.3×10^-7,respectively.

Key words: Photoacoustic spectrometry, Rare earth

Yan Hongtao, Deng Yanzhuo, Zeng Yun'e. Photoacoustic Spectrometry Investigation and Determination of Rare Earth Ions Ho³⁺ and Nd³⁺ in a Solution[J]. Chemical Research in Chinese Universities, 1988, 4(2): 25-30.

[1]	KE Yuqiu, GUO Wei, JIN Lanlan, QIAO Lei, YANG Huan, HU Shenghong. Direct Quantitative Determination of Rare Earth Elements in REE-rich Mineral Powders by LA-ICP-MS [J]. Chemical Research in Chinese Universities, 2017, 33(3): 360-364.
[2]	GOU Ruhu, WANG Yaling, YANG Rudong, LAN Yan. Luminescent Properties of Terbium(Ⅲ) and Europium(Ⅲ) Complexes with Six 4-Acetyl-bispyrazolones [J]. Chemical Research in Chinese Universities, 2014, 30(2): 190-193.
[3]	LIU Ying, SUN Cuihong, LI Xiaofang, ZHANG Shaowen. Selective 3,4-Polymerization Mechanism of Isoprene Catalyzed by Rare Earth Alkyl Complexes [J]. Chemical Research in Chinese Universities, 2014, 30(1): 114-118.
[4]	XU Zhen-he, GAO Yu, GE Xin, SUN Ya-guang. Facile Chemical Conversion Synthesis and Luminescence Properties of Uniform YF₃ Nanowires [J]. Chemical Research in Chinese Universities, 2013, 29(1): 1-5.
[5]	ZHANG Jin-li, CHEN Bo-wei, LUO Xuan, DU Kai. Eu(III) Complex-doped PMMA with Fast Radiation Rate and High Emission Quantum Efficiency [J]. Chemical Research in Chinese Universities, 2012, 28(6): 1054-1057.
[6]	GUO Li, YUAN Hong-ming, HUANG Ke-ke, YUAN Lin, LIU Shao-kong and FENG Shou-hua*. Hydrothermal Synthesis, Characterization and Magnetic Properties of Rare arth Iron Garnets Sm₃Fe₅O₁₂ and Eu₃Fe₅O₁₂ [J]. Chemical Research in Chinese Universities, 2011, 27(5): 715-719.
[7]	FANG Xiao-niu , CHEN Wen-tong , LIU Dong-sheng. Hydrothermal Synthesis, Crystal Structure and Spectroscopic Investigations of [Y(C6NO2H5)3(H₂O)₂]_n(1.5nZnCl₄)·nH₂O with Unprecedented Polycationic Chains [J]. Chemical Research in Chinese Universities, 2008, 24(5): 529-533.
[8]	JIN Hua, QI Yan-fei, QIN Chao, WANG Xin-long, WANG En-bo, XU Lin. [Ce(H₂ O)₇ Al(OH)₆ Mo₆O₁₈]·4H₂ O: A New One-dimensional Zigzag Chainlike Structure of Anderson Cluster Linked by Cerium Ions [J]. Chemical Research in Chinese Universities, 2005, 21(6): 637-640.
[9]	XU Xiao-yan, NI Xu-feng, XU Hong, SHEN Zhi-quan. Polymerization of n-Hexyl Isocyanate Initiated by Novel Rare Earth Tris (2,6-di-tert-butyl-4-methylphenolate) [J]. Chemical Research in Chinese Universities, 2005, 21(2): 224-226.
[10]	GE Yue, YUE Zheng-yu, GAO Jin-sheng, YAN Peng-fei. Some Rare Earth Metallic Organohydrides with Biindenyl as the Ligand [J]. Chemical Research in Chinese Universities, 2001, 17(3): 338-340.
[11]	JIANG Jian-zhuang, LIU Wei, SUN Xuan, ZHANG Xian-xi, NG Dennis K. P.. Isolation and Spectroscopic Characterization of Protonated Mixed [Tetrakis (4-pyridyl)porphyrinato] (phthal ocyaninato)Rare Earth (Ⅲ)Double-decker Compounds [J]. Chemical Research in Chinese Universities, 2001, 17(2): 134-142.
[12]	XU Yao-hua, WANG Dan, FENG Shou-hua, PANG Wen-qin, YUE Yong . Mild Hydrothermal Synthesis, Characterization and Properties of Na₅Ce(PO₄)₃, Na₃Yb₂(PO₄)₃·H₂O and Na_5-2xYb₂xCe_1-x(PO₄)₃·yH₂O [J]. Chemical Research in Chinese Universities, 2000, 16(4): 287-300.
[13]	PAN Zhi-da, SUN Jun-quan, YANG Shi-lin . Kinetics and Mechanism of the Polymerization of Methyl Methacrylate in a Y(acac)₃/n-BuMgCl System [J]. Chemical Research in Chinese Universities, 2000, 16(1): 61-66.
[14]	BI Li-hua, LIU Jing-hua, WANG En-bo, HUANG Ru-dan, YU Yong-zhang, WU Ping-song . Syntheses and Liquid Crystal Properties of New Rare Earth Sandwich-Type Heteropoly Compounds [J]. Chemical Research in Chinese Universities, 1999, 15(4): 364-366.
[15]	SHI Lei, SUN Ren-an, YANG Ren-wu, YU Shu-wen, LIAO Shi-jian, YU Dao-rong . The Cycloaddition Reactions Catalyzed by Some Rare Earth Chlorides [J]. Chemical Research in Chinese Universities, 1999, 15(4): 381-384.

Photoacoustic Spectrometry Investigation and Determination of Rare Earth Ions Ho³⁺ and Nd³⁺ in a Solution

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments