Chemical Research in Chinese Universities ›› 1987, Vol. 3 ›› Issue (2): 32-37.

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CIDNP of Diecyl Peroxides Studies on the Kinetics of Decomposition of Diacyl Peiroxides Ⅷ in the Decomposition of Diacyl Peroxides

Liu Youcheng, Guo Qingxiang, Liu Peiqi   

  1. Department of Chemistry, Lanzhou University
  • Received:1987-03-27 Online:1987-12-24 Published:2011-09-07

Abstract: 1H CIDNP spectra recorded during the decomposition of aliphatic diacyl peroxides ((RCOO)2 R=n-C H (1),n-c7H11(2)) in ODCB in the presence of scavengers,such as I2C2H5I,(CH3)2CHI,and CH2=CHCH2 Br show multiplet effect for the scavenged products,RX(X=Br,I) and for disproportionation products,R-H.The reactionmechanism is discussed in terms of radical pair theory.