Chemical Research in Chinese Universities ›› 1985, Vol. 1 ›› Issue (2): 9-15.

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STUDIES ON BORON COMPOUNDS (Ⅱ)--SYNTHESIS AND PROPERTIES OF BORON CONTAINING BIS(π-ARENE)IRON(Ⅱ)COMPOUNDS

Zhang Lun, Fang Xingin, Zhang Guomin   

  1. Department of Chemistry, Wuhan University, Wuhan
  • Received:1985-02-02 Online:1985-11-24 Published:2011-09-07

Abstract: Thirteen bis(π-arene)iron(Ⅱ) compounds were synthesized.They are [Ar FelB12H12(Ar=C6H6;MeC6H5;EtC6H5;n-PrC6H5;t-Pr-C6H5;p-Me2C6H4,o-Me2C6H4; 1,2,4-Me3C6H3;1,3,5-Me3C6H3;and 1,2,4,5-MeC6h2)and [Ar2Fe][PF6]2(Ar=p-Me2C6H4;and These compounds have all been identified by elemental analysis and IRspectra,some of them by MS and 1HNMR.The thermal behavior of these compounds has been investigated by DTA-TGmethod and IRspectroscopy,and their thermal stability was described.