Chemical Research in Chinese Universities ›› 1985, Vol. 1 ›› Issue (2): 55-62.

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SYNTHESIS AND SPECTRAL STUDIES OF(μ-PHENYLTHIO) (μ-ALKYLTHIO) HEXACARBONYLDIIRON COMPLEXES

Song Licheng, Hu Qingmei, Liu Xiangyang, Wang Jicao   

  1. Department of Chemistry, Nankai University
  • Received:1985-02-08 Online:1985-11-24 Published:2011-09-07

Abstract: Through reductive reaction between PhL1and μ-S2Fe(CO)6,tollowed by nucleophilicsubstitution of the intermediate (μ-PhS)(μ-LaS)Fe2(CO)6toward RX,nine Fe-S Clus-ter Complexes of (μ-PhS)(μ-LaS)Fe2(CO)6series have been synthesized. The influence of RX structures on the activities in nucleophilic substitution has been examined and possible steroisomers and isomer ratios of the complexes determined.