CRCU

Chemical Research in Chinese Universities ›› 1985, Vol. 1 ›› Issue (2): 114-120.

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STUDIES ON METHYL METHACRYLATE POLYMERIZATION INITIATED WITH PIPERIDINE DERIVATIVES AND ORGANIC PEROXIDE SYSTEMS

Zhang Jingyi1, Qiu Kunyuan2, Feng Xinde2   

  1. 1. The First Branch of Peking University, Beijing;
    2. Chemistry Department, Peking University, Beijing
  • Received:1985-01-04 Online:1985-11-24 Published:2011-09-07

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Abstract: The polymerization of methyl methacrylate(MMA) initiated with piperidine derivatives,such as,piperidine(P),2,2,6,6-tetramethyl-4-hydroxyl piperidine(TMP),N-ethyl iperidine(NEP),1,2,2,6,6-pentamethyl-4-hydroxyl piperidine(PMP),and organic peroxides,such as,benzoyl peroxide(BPO),lauryl peroxide(LPO),f-butyl hydroperoxide (TBH),t-butyl peroxybenzoate(TBPB) systems was studied and discussed in this paper.The polymerization rate equation and the activation energy of polymerization were determined respectively.