Rh-loaded High-entropy Oxide for Efficiently Catalyzing the Reverse Water-Gas Shift Reaction

doi:10.1007/s40242-024-4079-4

Chemical Research in Chinese Universities ›› 2024, Vol. 40 ›› Issue (6): 970-977.doi: 10.1007/s40242-024-4079-4

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Rh-loaded High-entropy Oxide for Efficiently Catalyzing the Reverse Water-Gas Shift Reaction

WANG Ke^1,2, ZHANG Rui^1,2, WANG Huilin^1,2, ZHANG Lingling^1,2, WANG Zijian^1,2, WANG Xiao^1,2, SONG Shuyan^1,2, ZHANG Hongjie^1,2,3

1. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
2. School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, P. R. China;
3. Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

Received:2024-03-30 Online:2024-12-01 Published:2024-10-26
Contact: WANG Xiao,wangxiao@ciac.ac.cn;SONG Shuyan,songsy@ciac.ac.cn;ZHANG Hongjie,hongjie@ciac.ac.cn E-mail:wangxiao@ciac.ac.cn;songsy@ciac.ac.cn;hongjie@ciac.ac.cn
Supported by:
This work was supported by the National Science and Technology Major Project of China (No. 2021YFB3500700), the National Natural Science Foundation of China (Nos. 22020102003, 22025506, 22271274), and the Program of Science and Technology Development Plan of Jilin Province, China (Nos. 20230101035JC, 20230101022JC).

Abstract

Abstract: Establishing efficient CO₂ hydrogenation technology based on the reverse water-gas shift (RWGS) reaction can effectively alleviate environmental problems while providing high-value-added products. The development of suitable advanced supports is the key to improving the catalytic activity and selectivity. Herein, we designed and synthesized a new type of spinel-phase high entropy oxides [(FeCrMnAlGa)₃O_4-x, FMG], which exhibited remarkable RWGS performance after loading small-size Rh nanoparticles. The CO yield was as high as 145.5 μmol_CO·g_cat^-1·s^-1 at 380 ℃ and the CO selectivity was nearly 100%. Moreover, the catalyst retained over 95% of the initial activity after 25 h of continuous catalyzing. Experimental and structural studies reveal that the FMG support has elemental synergy and high-entropy stability, which affect the Rh dispersion and oxygen vacancy generation, in turn achieving superior catalytic performance.

Key words: High entropy oxide (HEO), Reverse water-gas shift (RWGS), Size effect, Elemental synergy

WANG Ke, ZHANG Rui, WANG Huilin, ZHANG Lingling, WANG Zijian, WANG Xiao, SONG Shuyan, ZHANG Hongjie. Rh-loaded High-entropy Oxide for Efficiently Catalyzing the Reverse Water-Gas Shift Reaction[J]. Chemical Research in Chinese Universities, 2024, 40(6): 970-977.

References

[1] Tountas A. A., Ozin G. A., Sain M. M., Nat. Catal., 2021, 4, 934.
[2] Su X., Yang X., Zhao B., Huang Y., J. Energy Chem., 2017, 26, 854.
[3] Williamson D. L., Herdes C., Torrente-Murciano L., Jones M. D., Mattia D., ACS Sustainable Chem. Eng., 2019, 7, 7395.
[4] Chen Y., Ma L., Zhang R., Ye R., Liu W., Wei J., Ordomsky V. V., Liu J., Appl. Catal. B, 2022, 312, 121393.
[5] Zhang R., Wang X., Wang K., Wang H., Liu L., Wu X., Geng B., Chu X., Song S., Zhang H., Adv. Energy Mater., 2023, 13, 2203806.
[6] Zhang R., Wang X., Wang K., Wang H., Song S., Zhang H., Mater. Chem. Front., 2023, 7, 6411.
[7] Millet M.-M., Tarasov A. V., Girgsdies F., Algara-Siller G., Schloegl R., Frei E., ACS Catal., 2019, 9, 8534.
[8] Xu J., Wang Y., Wang K., Zhao M., Zhang R., Cui W., Liu L., Bootharaju M. S., Kim J. H., Hyeon T., Zhang H., Wang Y., Song S., Wang X., Angew. Chem., Int. Ed., 2023, 62, e202302877.
[9] Wang J., Li G., Li Z., Tang C., Feng Z., An H., Liu H., Liu T., Li C., Sci. Adv., 2017, 3, e1701290A.
[10] Chen Z., Jiang Q., An H., Zhang J., Hao S., Li X., Cai L., Yu W., You K., Zhu X., Li C., ACS Catal., 2022, 12, 7719.
[11] Kattel S., Liu P., Chen J. G., J. Am. Chem. Soc., 2017, 139, 9739.
[12] Cisneros S., Chen S., Fauth C., Abdel-Mageed A. M., Pollastri S., Bansmann J., Olivi L., Aquilanti G., Atia H., Rabeah J., Parlinska-Wojtan M., Brückner A., Behm R., Appl. Catal., B, 2022, 317, 121748.
[13] Wang Q., Liu X., He D., Wang D., Mater. Today, 2023, 70, 218.
[14] Wang Y., Mi J., Wu Z.-S., Chem Catal., 2022, 2, 1624.
[15] Ye L., Chen M., Niu L., Gong Y., Li C., Chem. Eng. J., 2024, 480, 148122.
[16] Pan Y., Liu J.-X., Tu T.-Z., Wang W., Zhang G.-J., Chem. Eng. J., 2023, 451, 138659.
[17] Kante M. V., Weber M. L., Ni S., van den Bosch I. C. G., van der Minne E., Heymann L., Falling L. J., Gauquelin N., Tsvetanova M., Cunha D. M., Koster G., Gunkel F., Nemšák S., Hahn H., Estrada L., Baeumer C., Acs Nano, 2023, 17, 5329.
[18] Feng D., Dong Y., Zhang L., Ge X., Zhang W., Dai S., Qiao Z.-A., Angew. Chem., Int. Ed. 2020, 59, 19503.
[19] Xu H., Zhang Z., Liu J., Chi-Linh D.-T., Chen H., Xu S., Lin Q., Jiao Y., Wang J., Wang Y., Chen Y., Dai S., Nat. Commun., 2020, 11, 3908.
[20] Chen H., Jie K., Jafta C. J., Yang Z., Yao, S., Liu, M., Zhang Z., Liu J., Chi M., Fu J., Dai S., Appl. Catal., B, 2020, 276, 119155.
[21] Fan M.-Y., Wang J.-J., Zhao J., Zhang H., Ma T.-Y., Han X.-P., Hu W.-B., Rare Met. 2024, 43,1537.
[22] Chen H., Lin W., Zhang Z., Jie K., Mullins D. R., Sang X., Yang S.-Z., Jafta C. J., Bridges C. A., Hu X., Unocic R., Fu J., Zhang P., Dai S., ACS Mater. Lett., 2019, 1, 83.
[23] Zhu S., Chen Y., Somayaji V., Novello P., Chacko D., Li F., Liu J., ACS Appl. Mater. Interfaces 2023, 15, 31384.
[24] Zhao J., Bao J., Yang S., Niu Q., Xie R., Zhang Q., Chen M., Zhang P., Dai S., Acs Catal., 2021, 11, 12247.
[25] Portillo E., Gandara-Loe J., Reina T. R., Pastor-Perez L., Sci. Total Environ., 2023, 857, 159394.
[26] Elsernagawy O. Y. H., Hoadley A., Patel J., Bhatelia T., Lim S., Haque N., Li C. E., J. CO₂ Util. 2020, 41, 101280.
[27] Wang H., Gao Z., Sun B., Mu S., Dang F., Guo X., Ma D., Shi C., Chem. Catal., 2023, 3, 100768.
[28] Fracchia M., Manzoli M., Anselmi-Tamburini U., Ghigna, P., Scr. Mater., 2020, 188, 26.
[29] Yang Y., Liu J., Liu F., Wu D., Fuel, 2020, 276, 118093.
[30] Wang C., Sun H., Liu X., Jin X., Feng Y., Shi H., Wang D., Zhang Y., Wang Y., Yan Z., Fuel, 2023, 345, 128238.
[31] Liao W., Yue M., Chen J., Wang Z., Ding J., Xu Y., Bai Y., Liu X., Jia A., Huang W., Zhang Z., ACS Catal., 2023, 13, 5767.
[32] Yan B., Wu Q., Cen J., Timoshenko J., Frenkel A. I., Su D., Chen X., Paris J. B., Stach E., Orlov A., Chen J. G., Appl. Catal. B, 2018, 237, 1003.
[33] Yentekakis I. V., Goula G., Hatzisymeon M., Betsi-Argyropoulou I., Botzolaki G., Kousi K., Kondarides D. I., Taylor M. J., Parlett C. M. A., Osatiashtiani A., Kyriakou G., Holgado J., Lambert R., Appl. Catal., B, 2019, 243, 490.
[34] Dostagir N. H. M., Rattanawan R., Gao M., Ota J., Hasegawa J.-Y., Asakura K., Fukouka A., Shrotri A., ACS Catal., 2021, 11, 9450.
[35] Bagus P. S., Nelin C. J., Brundle C. R., Crist B. V., Lahiri N., Rosso K. M., J. Chem. Phys., 2021, 154, 094709.
[36] Ünveren E., Kemnitz E., Hutton S., Lippitz A., Unger W. E. S., Surf. Interface Anal., 2004, 36, 92.
[37] Penke Y. K., Anantharaman G., Ramkumar J., Kar K. K., J. Hazard. Mater., 2019, 364, 519.
[38] Tago T., Kataoka N., Tanaka H., Kinoshita K., Kishida S., Procedia Eng., 2017, 216, 175.
[39] Zhang X., Huang H., Zhang Y., Liu D., Tong N., Lin J., Chen L., Zhang Z., Wang X., ACS Omega, 2018, 3, 14469.
[40] Khanchi M., Mousavian S. M. A., Soltanali S., Int. J. Energy Res., 2022, 46, 3057.
[41] Bao H., Sun X., Jiang Z., Huang Y., Wang J., Chin. J. Catal., 2014, 35, 1418.
[42] Chen H., Sun Y., Yang S., Wang H., Dmowski W., Egami T., Dai, S., Chem. Commun., 2020, 56, 15056.
[43] Zhang M., Duan X., Gao Y., Zhang S., Lu X., Luo K., Ye J., Wang X., Niu Q., Zhang P., Dai S., ACS Appl. Mater. Interfaces, 2023, 15, 45774.

Rh-loaded High-entropy Oxide for Efficiently Catalyzing the Reverse Water-Gas Shift Reaction

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