Recent Advances in Helical Polyisocyanide-based Block Copolymers: Preparation, Self-assembly and Circularly Polarized Luminescence

doi:10.1007/s40242-023-3170-6

Abstract

Abstract: Polyisocyanides and their block copolymers have widespread applications in many fields due to their unique helix and self-assembly properties. At first, the latest progress in the preparation of helical polyisocyanide-based block copolymers via the method of one-pot sequential controlled synthesis and stepwise polymerization was highlighted in this minireview. Various categories of helical polyisocyanide-based copolymers including amphiphilic block copolymers, UV-response block copolymers, π-conjugated block copolymers, etc., have been prepared successfully. Moreover, recent advances in the self-assembly and circularly polarized luminescence performance of amphiphilic and π-conjugated helical polyisocyanide-based copolymers have been introduced, respectively. We hope this minireview will not only inspire more interest in developing helical polyisocyanide-based copolymers, but also encourage further progress in the field of building artificial functional materials.

Key words: Helical polyisocyanide, Block copolymer, Self-assemble, Circularly polarized luminescence

ZHOU Li, CHEN Kun, ZHOU Xing-Yu, WU Zong-Quan. Recent Advances in Helical Polyisocyanide-based Block Copolymers: Preparation, Self-assembly and Circularly Polarized Luminescence[J]. Chemical Research in Chinese Universities, 2023, 39(5): 719-725.

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